Chap 11 Coordination Compound Structures 11.1 Configurations and Magnetism of Coordination Compounds X 11.2 Chemical Bonding Theory in Complexes
Chap 11 Coordination Compound Structures §11.2 Chemical Bonding Theory in Complexes §11.1 Configurations and Magnetism of Coordination Compounds
11.1 Configurations and Magnetism of Coordination Compounds 11.1.1 Configurations of Coordination Compounds 1.configurations 2.isomers 11.1.2 Magnetism of Coordination Compounds
11.1 Configurations and Magnetism of Coordination Compounds 11.1.1 Configurations of Coordination Compounds 1. configurations 2. isomers 11.1.2 Magnetism of Coordination Compounds
11.1.1 Configurations of coordination compounds 1.Geometric arrangements of atoms in a coordination compound: 与配位数及配体种类有关 0◆0 00-0 88 dodecahedral 正十二面体形 linear tetrahedral Square planer octahedral (8个顶点) NH3 12 2 Ag(NH3)2 -NH3 H
11.1.1 Configurations of coordination compounds 1. Geometric arrangements of atoms in a coordination compound: 与配位数及配体种类有关 linear Square planer tetrahedral octahedral dodecahedral 正十二面体形 (8个顶点) + 3 2 Ag(NH )
H CH H 八面体形 CoEDTA Fe(CN) O HO-C-H2C CH2-C-OH HO-C-H2C N-CH.CHN CH2-C-OH 0 D
O HO-C-H2C O HO-C-H2C N-CH2 -CH2 -N O CH2 -C-OH O CH2 -C-OH 乙二胺四乙酸 八面体形 3− Fe(CN)6
Hgl; N SbCI Square pyramidal Triangular 四方锥形 平面三角形 Triangle bipyramidal 三角双锥形 Fe(CO)s
Triangular 平面三角形 Square pyramidal 四方锥形 Triangle bipyramidal 三角双锥形 − HgI 3 2− SbCl5 Fe(CO)5