第五章量子微纳光学5.1分子荧光5.2纳米结构近场区域偶极子弛豫系数5.3SPP增强分子荧光的前沿进展5.4SPP的量子性5.5基于超表面的量子性质5.6基于拓扑光子结构的量子性质5.7微纳尺度腔量子电动力学及应用古英ygu@pku.edu.cn
1 第五章 量子微纳光学 5.1 分子荧光 5.2 纳米结构近场区域偶极子弛豫系数 5.3 SPP增强分子荧光的前沿进展 5.4 SPP 的量子性 5.5 基于超表面的量子性质 5.6 基于拓扑光子结构的量子性质 5.7 微纳尺度腔量子电动力学及应用 古英 ygu@pku.edu.cn
5.1分子荧光（molecularfluorescence，MF)Luminescence(发光）:anemissionofultravioletvisible or infrared photons from an electronicallyexcitedspeciesincludingfluorescence(荧光）andphosphorescence（磷光）MF的作用：是一种很好的分析各种类的成份的工具；可分析各种活体生物结构和动力学过程：还可以做高灵敏度的传感器Molecular Fluorescence:principles and applicationsBernardValeur,2001Wiley-VCHVerlagGmbH2
2 Molecular Fluorescence: principles and applications Bernard Valeur, 2001 Wiley-VCH Verlag GmbH 5.1 分子荧光 (molecular fluorescence, MF) Luminescence (发光）: an emission of ultraviolet, visible or infrared photons from an electronically excited species， including fluorescence (荧光）and phosphorescence (磷光） MF 的作用：是一种很好的分析各种类的成份的工具； 可分析各种活体生物结构和动力学过程；还可以做 高灵敏度的传感器
MF的发展简史：1565N.MonardesEmissionof lightby an infusion of wood Lignum Nephriticum(firstreportedobservationoffluorescence)1602V.CascarioloEmission of lightbyBolognesestone(firstreportedobservation ofphosphorescence)1640LicetusStudy of Bolognese stone.First definition asa non-thermal lightemission1833D.BrewsterEmissionoflightbychlorophyllsolutionsandfluorsparcrystals1845J. HerschelEmissionoflightbyquininesulfatesolutions(epipolicdispersion1842E. BecquerelEmissionof lightbycalciumsulfideuponexcitationintheUVFirststatement thatthe emitted lightis of longer wavelengththan the incident light1852G.G. StokesEmissionof lightbyquinine sulfatesolutionsuponexcitationintheUV (refrangibilityoflight)1853G. G. StokesIntroductionofthetermfHuorescence1858E.BecquerelFirstphosphoroscope1867Firstfluorometricanalysis (determinationofAl(III)bytheF.Goppelsroderfluorescenceof itsmorinchelate)1871A. Von BaeyerSynthesisoffluorescein1888E.WiedemannIntroductionofthetermluminescence3MolecularFluorescence:principlesandapplicationsBernardValeur.2001Wiley-VCHVerlagGmbH
3 Molecular Fluorescence: principles and applications Bernard Valeur, 2001 Wiley-VCH Verlag GmbH MF 的发展简史：
1905,E. L. Nichols andFirstfluorescenceexcitation spectrum ofa dye1910E.Merrit1907E. L. Nichols andMirrorsymmetrybetweenabsorptionandfluorescenceE.Merritspectra1918J. PerrinPhotochemicaltheoryofdyefluorescence1919Stern and VolmerRelationforfluorescencequenching1920F.WeigertDiscoveryof the polarization ofthefluorescence emitted bydye solutions1922S. J. VavilovExcitation-wavelengthindependenceof thefluorescencequantumyield1923S.J. Vavilov andFirststudyof thefluorescencepolarizationofdyesolutionsW. L. Levshin1924S. J. VavilovFirst determination of fluorescence yield of dye solutions1924F.PerrinQuantitativedescription of staticquenching (activespheremodel1924F.PerrinFirst observation of alpha phosphorescence (E-type delayedfluorescence)1925F.PerrinTheoryof fluorescencepolarization(influenceofviscosity)1925W. L. LevshinTheoryofpolarized fluorescenceand phosphorescence1925J. PerrinIntroduction of thetermdelayed fluorescencePrediction of long-range energytransfer4MolecularFluorescence:principlesandapplicationsBernardValeur.2001Wiley-VCHVerlagGmbH
4 Molecular Fluorescence: principles and applications Bernard Valeur, 2001 Wiley -VCH Verlag GmbH
1926E.GaviolaFirstdirectmeasurementofnanosecondlifetimesbyphasefluorometry(instrumentbuiltinPringsheim'slaboratory1926F.PerrinTheory of fluorescencepolarization (sphere).Perrin's equationIndirectdeterminationoflifetimesinsolution.Comparisonwithradiativelifetimes1927Demonstration of resonanceenergytransferin solutionsE.Gaviola andP.Pringsheim1928E. Jette and W.FirstphotoelectricfluorometerWest1929F.PerrinDiscussiononJeanPerrin'sdiagramfortheexplanationofthedelayed fluorescence by the intermediatepassagethroughametastable stateFirst qualitative theory of fluorescencedepolarization byresonanceenergytransfer1929J. Perrin andSensitizeddyefluorescenceduetoenergytransferChoucroun1932F.PerrinQuantummechanicaltheoryof long-rangeenergytransferbetweenatoms1934F. PerrinTheoryoffluorescencepolarization(ellipsoid)1935A.JablonskiJablonskis diagram1944Lewis andKashaTriplet state1948Th.ForsterQuantummechanicaltheory ofdipole-dipoleenergytransfer5MolecularFluorescence:principlesandapplicationsBernardValeur.2001Wiley-VCHVerlagGmbH
5 Molecular Fluorescence: principles and applications Bernard Valeur, 2001 Wiley -VCH Verlag GmbH