Chapter 13Nitrogen Containing Organic Compounds
Chapter 13 Nitrogen Containing Organic Compounds
13.1 Nitro Compounds13.1.1 Nomenclature and PhysicPropertiesR-NO2RNORONORONO2NitriteNitrocompoundNitrateNitric compoundNomenclature:NO, as a substituted groupR
13.1 Nitro Compounds 13.1.1 Nomenclature and Physic Properties R-NO2 R O N O 2 R N O R O N O Nitro compound Nitrate Nitric compound Nitrite Nomenclature: NO2 as a substituted group R N O O π 3 4 R N O O
13.1.2 Preparation13.1.2.1 Gaseous nitraton of aliphatichydrocarbonsCH3CH,CHNOCH,CHCH3400℃CHCH,CH3+HONO2NO2CH3CHNO2CH3NO2
13.1.2 Preparation 13.1.2.1 Gaseous nitraton of aliphatic hydrocarbons 400℃ HONO2 CH3CH2CH2NO2 CH3CHCH3 NO2 CH3CH2NO2 CH3NO2 CH3CH2CH3 +
13.1.2.2 Nucleophilic substitution+CH3(CH2)6CH,NO2 +CH3(CH2)CH,ONOCH3(CH2)6CH,I+AgNO211%83%RCH,NO2CH2-RCH,ONO
13.1.2.2 Nucleophilic substitution 83% 11% CH3 (CH2 )6CH2I+ AgNO2 CH3 (CH2 )6CH2NO2 +CH3 (CH2 )6CH2ONO -O N O : + CH2 X R RCH2NO2 RCH2ONO + X O - :N O
13.1.2.3 Oxidation of tertiary aminesCH3CH3KMnO4CH3 --C一NH2CH-C-NO2CH3CH383%
13.1.2.3 Oxidation of tertiary amines CH3 C NH2 CH3 CH3 KMnO4 CH3 C NO2 CH3 CH3 83%