A+bB→F 1moA与 b mol b反应,A扩散到RR界面 上的速度为B的1/b,B在RR界面上CB为零 因此 GIR L BL R’L a
A+bB→ F 1mol A与b mol B反应,A扩散到RR′界面 上的速度为B的1/b,B在RR′界面上CB 为零, 因此 G I R L G I L G I L pG pG pG pi CBL CBL CBL Ci pi =0 pi =0 CBi yG yR yG yL yG yL G’ I’ R’ L’ G’ I’ L’ G’ I’ L’ (a) (b) (c) 图 3.4 瞬时反应浓度分布情况 (a) CBL < CC BL (b) CBL = CC BL (c) CBL >CC BL A 组分, B 组分
R L BL BL B R L L (b) (a) cbl <c bl (b) CBl-C bl (c) CBl >C bl A组分, B组分 瞬时反应浓度分布情况
G I R L G I L G I L pG pG pG pi CBL CBL CBL Ci pi=0 pi=0 CBi yG yR yG yL yG yL G’ I’ R’ L’ G’ I’ L’ G’ I’ L’ (a) (b) (c) 图 3.4 瞬时反应浓度分布情况 (a) CBL < CC BL (b) CBL = CC BL (c) CBL >CC BL A 组分, B 组分 G I R L G I L G I L pG pG pG pi CBL CBL CBL Ci pi =0 pi =0 CBi yG yR yG yL yG yL G’ I’ R’ L’ G’ I’ L’ G’ I’ L’ (a) (b) (c) 图 3.4 瞬时反应浓度分布情况 (a) CBL < CC BL (b) CBL = CC BL (c) CBL >CC BL A 组分, B 组分 瞬时反应浓度分布情况
DC BBL R VLVR D BL DO (11) B L R R D. B BL (12) VL-VR (11)+ n b (12) yL=(DC,o B BL (13) B/N D,C N=(DC;+ BL )/y2 (14)
N DCy D C y y b i R B BL L R ' = = − 1 (3 - 4 7 ) y DCN R i = ' (3 - 4 8 ) y y D CN b L R B BL − = ' 1 (3 -49) y DC D Cb L i N B BL = ( + ) / ' (3 -50) N DC D Cb y i B BL L ' = ( + ) / (3 -51) R i y DC N = ' y y b D C N L R ' B BL 1 − = (10) (11) (12) (13) (14) (11 ) + (12 ) L R B BL B y y D C N − ' =
根据式(8) DnC (DCi+ b)/yi b C E D L DC.+DC/b 1 B BL DO D c. b (15)
根据式(8) (15) C b C D D D C D C D C b y D C y b D C D C k k E i B BL i i BL L i L B BL i L L 1 1 / 1 ( )/ ' = + + = + = = L L k k E / =
D B D扩散系数比 BL 计量浓度比 Cb 则(15)就可写成: E=1+rS (16)
D D r = B C b C S i = BL 令 扩散系数比 计量浓度比 则 (15)就可写成: E =1+ rS (16)