Organic Chemistry,6th Edition L.G.Wade,Jr. Chapter 2 Structure and Properties of Organic Molecules Jo Blackburn Richland College,Dallas,TX Dallas County Community College District ©2006，Prentice Hall
Chapter 2 Structure and Properties of Organic Molecules Organic Chemistry, 6th Edition L. G. Wade, Jr. Jo Blackburn Richland College, Dallas, TX Dallas County Community College District © 2006, Prentice Hall
Wave Properties of Electrons Standing wave vibrates in fixed location. Wave function,y,mathematical description of size,shape,orientation. Amplitude may be positive or negative. Node:amplitude is zero. nodal plane nucleus represented by nucleus wave function > (instantaneous picture) nodal plane
Chapter 2 2 Wave Properties of Electrons • Standing wave vibrates in fixed location. • Wave function, , mathematical description of size, shape, orientation. • Amplitude may be positive or negative. • Node: amplitude is zero. =>
Wave Interactions Linear combination of atomic orbitals >on different atoms produce molecular orbitals >on the same atom give hybrid orbitals. Conservation of orbitals. Waves that are in phase add together. Amplitude increases. Waves that are out of phase cancel out. Chapter 2 3
Chapter 2 3 Wave Interactions • Linear combination of atomic orbitals ➢on different atoms produce molecular orbitals ➢on the same atom give hybrid orbitals. • Conservation of orbitals. • Waves that are in phase add together. Amplitude increases. • Waves that are out of phase cancel out. =>
Bonding Region Electrons are close to both nuclei. bonding region ●入 electrons in this region nucleus 1 attract both nuclei nucleus 2 and mask the positive charges from repelling each other > Copyright2005 Pearson Prentice Hall.Inc
Chapter 2 4 Bonding Region • Electrons are close to both nuclei. =>
Sigma Bonding Electron density lies between the nuclei. A bond may be formed by s-s,p-p,s-p, or hybridized orbital overlaps. The bonding MO is lower in energy than the original atomic orbitals. The antibonding MO is higher in energy than the atomic orbitals. => Chapter 2 5
Chapter 2 5 Sigma Bonding • Electron density lies between the nuclei. • A bond may be formed by s-s, p-p, s-p, or hybridized orbital overlaps. • The bonding MO is lower in energy than the original atomic orbitals. • The antibonding MO is higher in energy than the atomic orbitals. =>