第十五章有机硅和有机钛化合物 15.1命名下列各化合物。 (1)(C6H5)2 SiCl2 (2)(CH3)3S-O-SCH3)3 (3)(CHa)2SI(OC2H52 (4)(C2 HS)2Si(OH)2 5)(C2H5)2PH (6)(A)(C6H3)2CH(CH3)2Br (B)(C6H5)2P-CH(CH3)2OH CH (7(A)(C6H52PCH3 (B)(CH)2P(CH3)2 ( C)(C6H5), P(CH3),OH (8)(A)(CH3 CH2O)3P--CHCN (9)(A)(cH)P=CH2 (10)(A)( CH3CHO)4TI (11)(A)(CH3CH2 CH2 CH2O)4Ti (B)C,HOH (12)(A)TI(OH)4 (B)CH3-CHOH (13)(A)CH3 CHO-IOOC(CH2)14 CH(CH3)2(B)CH3-CHOH 答:(1)二苯基二氯硅烷(2)六甲基二(甲)硅醚(3)二甲基二乙氧基硅烷 (4)二乙基硅二醇(5)二乙基膦(6)碘化四乙基膦 (7)原钛酸异丙酯 (8)二硬脂酰氧基钛酸二乙酯
第十五章 有机硅和有机钛化合物 15.1 命名下列各化合物。 (C6H5) 2SiCl2 (CH3) 3Si O Si(CH3) 3 (CH3) 2Si(OC2H5) 2 (C2H5) 2Si(OH)2 (C2H5) 2PH (C6H5) 2P CH(CH3) 2Br CH3 (C6H5) 2P CH(CH3) 2OH CH3 (C6H5) 2PCH3 (C6H5) 2P(CH3) 2I (C6H5) 2P(CH3) 2OH (CH3CH2O)3P CHCN (C6H5) 3P CH2 (CH3CHO)4Ti CH3 (CH3CH2CH2CH2O)4Ti C2H5OH Ti(OH)4 CH3 CHOH CH3 CH3 CHO Ti OOC(CH2) 14CH(CH3) 2 CH3 CH3 CHOH CH3 (1) (3) (5) (6) (4) (2) (A) (B) (11) (A) (B) (12) (A) (A) (B) (6) (B) + _ (A) + _ (7) (C) + _ + _ (8) + _ (9) (10) (A) (A) (A) (B) (13) 3 答： （１）二苯基二氯硅烷 （２）六甲基二（甲）硅醚 （３）二甲基二乙氧基硅烷 （４）二乙基硅二醇 （５）二乙基膦 （6）碘化四乙基膦 （7）原钛酸异丙酯 （8）二硬脂酰氧基钛酸二乙酯
152写出下列各化合物的构造式 (1)四乙基硅烷 (2)乙烯基三氯硅烷(3)六甲基二硅氧烷 (4)γ一氨基丙基三乙氧基硅烷(5)氧化三苯基膦(6)原钛酸正丁酯 :(1)(C2A4S 2)CH2 CH-SiCl3 (3)(cH3s;0sCH)3 (4)H2NCH2CH2CH2-SI(OC2H5)3 (5)(CH5)3P+O (6)(CH2 CH, CH, CH,O)Ti (CH3)2CI (CH2)14CH(CH3)2 3 153完成下列各反应式 (1)C2H,MgCl+ CH2 H2o (B) (2)CH,MgCl +sicl4 (3)(CHsC+3C。OH—·(4 (4)(CHy3 SiCI+C2HgMgCI (5)CH2CH S iCI (A)稀1 HBr OH (C H52 PCH3 CH3 CH=CI
15.2 写出下列各化合物的构造式。 （１）四乙基硅烷 （２）乙烯基三氯硅烷 （３）六甲基二硅氧烷 （4）γ－氨基丙基三乙氧基硅烷 （5）氧化三苯基膦（6）原钛酸正丁酯 H2NCH2CH2CH2 Si(OC2H5) 3 (C6H5)3P O (CH3CH2CH2CH2O)4Ti (CH3)2CHO Ti O C (CH2)14CH(CH3)2 O (4) (5) (6) (7) 3 15.3 完成下列各反应式。 (C6H5) 2PCH3 CH3CH CH2 HBr OH (6) + (A) (B)
OH (7)(cH52PH+CH!当 CH AqOH (8)CH3CH2C=0+(A)CH,cH2 CH3CH2 C-CHCN CH3CH2 CHO CH=CH +(A) H3C C CH CH (10) TiCL+ 4 CH3CH2 CH2 CH,OH 十 11)(C2HO)4T+4H3CH2CH2CH2OH—·(A)+(B) (12)(CH3CHO)4Ti+ H2o-(A)+(B) (13)(CH:CHO)Ti+(CH3)2 CH(CH2)14COOH 十 B:(1)(A)CH3 CH2 OMgCI (B)CHaCH2 CH,CH,OH (2)(A)CeHsSIC5 (3)(4)C2sH3 (4)闪)(cH3sc2H5 (5)(A)CH=CH-(0H2 (日)
OH (C6H5)2PH CH3I CH3I AgOH C O CH3CH2 CH3CH2 C CHCN CH3CH2 CH3CH2 CH3 H3C CHO CH3 H3C CH CH2 TiCl4 CH3CH2CH2CH2OH (C2H5O)4Ti CH3CH2CH2CH2OH (CH3 CHO)4Ti CH3 H2O (CH3 CHO)4Ti CH3 (CH3) 2CH(CH2) 14COOH (A) (B) (7) + (C) (8) + (A) (9) + (A) (10) + 4 (A) + (B) (11) + 4 (A) + (B) (12) + (A) + (B) (13) + (A) + (B)
(6)(A)(CgH5)2P-CH(CH3)2Br (B)(CHS)2P CH(CH),OH (7(A)(CH32PCH3 (B)(CH )2P(CH3)2 (C)(CgH) P(CH3),OH (8)(A)(CH3CH2 O)3P--CHCN (9)(A)(cH)2P=CH (10)(A)(CH3CHO)4 (11)(A)(CH3 CH2CH2 CH2O)4Ti (B)C2HSOH (12)(A) TI(OH)4 (B)CH3-CHOH CH (13)(A)CH3 CHO-T OOC(CH2)1CH(CH3)2(B CH3- CHOH H3 54钛酸酯偶联分成几类,各类对无机填料的适用性如何? 答:答案从略 15.5举例说明硅烷偶联剂提高复合材料基本性能的原理 答:答案从略
(C6H5)2P CH(CH3) 2Br CH3 (C6H5)2P CH(CH3) 2OH CH3 (C6H5) 2PCH3 (C6H5)2P(CH3)2I (C6H5)2P(CH3)2OH (CH3CH2O)3P CHCN (C6H5) 3P CH2 (CH3CHO)4Ti CH3 (CH3CH2CH2CH2O)4Ti C2H5OH Ti(OH)4 CH3 CHOH CH3 CH3 CHO Ti OOC(CH2) 14CH(CH3) 2 CH3 CH3 CHOH CH3 (A) (B) (11) (A) (B) (12) (A) (A) (B) (6) (B) + (A) + _ (7) (C) + _ + _ (8) + _ (9) (10) (A) (A) (A) (B) (13) 3 15.4 钛酸酯偶联分成几类，各类对无机填料的适用性如何？ 答：答案从略。 15.5 举例说明硅烷偶联剂提高复合材料基本性能的原理。 答：答案从略