《理论化学导论》（英文版）Solutions

11 z x y z x y

x米 6 12

12 x y x z y z 6

Hydrogen 4s Radial Function 0.20 0.15 0.10 0.00 10 20 30 r(bohr) bydrogen 4p Radial Function 006 0.04 0.00 002 20 30 40

13 0 10 20 30 40 -0.05 0.00 0.05 0.10 0.15 0.20 0.25 Hydrogen 4s Radial Function r (bohr) R4s(r) 0 10 20 30 40 -0.02 0.00 0.02 0.04 0.06 Hydrogen 4p Radial Function r (bohr) R4p(r)

Hydrogen 4d Radial Function 0.01 0.00 0.02 40 r(bohr) Hydrogen 4f Radial Function 0.02 0.01 10 20 30 40

14 0 10 20 30 40 -0.02 -0.01 0.00 0.01 0.02 0.03 Hydrogen 4d Radial Function r (bohr) R4d(r) 0 10 20 30 40 0.00 0.01 0.02 Hydrogen 4f Radial Function r (bohr) R4f(r)

7 Si 1s 120 100 Z=14 20 0.2 (bohr)

15 7. 0.0 0.1 0.2 0.3 0.4 0 20 40 60 80 100 120 Si 1s r (bohr) Radial Function R(r) Z=14