H N H H H aniline anilinium ion stabilized by overlap with the ring no overlap is possible aliphatic amine R一iH2+H+ R一NH3 NH3 stabilized by more endothermic overlap ○-iiH2 is less basic ○-H2+Ht aromatic amine
第二节胺 二、命名 多取代基化合物命名母体结构选择规则 酸>醛>酮>醇>胺>烯炔>烷
第二节 胺 二、命名 多取代基化合物命名母体结构选择规则 酸>醛>酮>醇>胺>烯炔>烷
CH3 CH3 CH2 =CHCH2NH2 C2H5NCHCH2CHCH2CH2CI 2一丙稀一1一胺 5-氯-N-乙基-N,3-二甲基-1-戊胺 NHCH: H2》 OCH3 N甲基苯胺 m-氨基苯甲醚 p一氨基苯甲酸
CH2 CHCH2 NH2 2—丙稀—1—胺 C2H5 NCH2 CH2 CHCH2 CH2 Cl CH3 CH3 5-氯-N-乙基-N,3-二甲基-1-戊胺 NHCH3 N-甲基苯胺 NH2 OCH3 H2N COOH m-氨基苯甲醚 p—氨基苯甲酸
CH3CH2CH2CHCH2NH2 CH3CH2CH2CH2N(CH3)2 CH3 2-methylpentanamine N,N-dimethylbutanamine 2一甲基戊胺 N,N-二甲基丁胺 CH3 NH2 NH2 CH3CH2CH2CHCH2CHCH2CH3 trans-1-amino-2methylcyclohexane 3-amino-5-methyloctane CH3 3一氨基一5一甲基辛烷 反式一1一氨基一2一甲基环已烷 CH3 CH3 CH3 CH3CH2CH2CHCH2CHCH2CH2-N-CH2CH2CH3 7654321 1-(methylpropylamino)-3,5-dimethyloctane (甲基丙氨基)一3,5一二甲基辛烷
CH3CH2CH2CHCH2CHCH2CH3 CH3 NH2 3-amino-5-methyloctane NH2 CH3 trans-1-amino-2methylcyclohexane CH3CH2CH2CHCH2CHCH2CH2 CH3 CH3 N CH2CH2CH3 CH3 8 7 6 5 4 3 2 1 1-(methylpropylamino)-3,5-dimethyloctane CH3CH2CH2CHCH2NH2 CH3 2-methylpentanamine CH3CH2CH2CH2N(CH3)2 N,N-dimethylbutanamine 3－氨基－5－甲基辛烷 反式－1－氨基－2－甲基环己烷 1－（甲基丙氨基）－3，5－二甲基辛烷 2－甲基戊胺 N,N-二甲基丁胺
NH2 trans-2-aminocyclohexanol OH 反式一2一氨基一环已醇 H2 (CH3)2NCH2CH2CHO CH3CH2CHCOOH 3-dimethylaminopropanal 2-aminobutanoic acid 3一二甲氨基己醛 2一氨基丁酸 3,5-二溴一对N,N-二甲氨基苯胺 Br N(CH3)2 3,5-dibromo-N,N-dimethylaniline (N.N-dimethyl-3,5-dibromobenzenamine) Br
NH2 OH trans-2-aminocyclohexanol (CH3) 2NCH2CH2CHO 3-dimethylaminopropanal CH3CH2CHCOOH NH2 2-aminobutanoic acid O2N NH2 p-nitroaniline CH3 NH2 or p-methylaniline (4-methylbenzenamine) (4-nitrobenzenamine) N(CH3) 2 Br Br 3,5-dibromo-N,N-dimethylaniline (N.N-dimethyl-3,5-dibromobenzenamine) 反式－2－氨基－环己醇 3－二甲氨基己醛 2－氨基丁酸 3，5－二溴－对N,N-二甲氨基苯胺