Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical ChemistryInorganic and Analytical ChemistryS/N:10421040Classification: Specialized Basic CourseApplicable to: Chemical Engineering and TechnicsFood Science and EngineeringPharmaceutical EngineeringMaterials Science andBiological EngineeringEngineeringTotal Hours for Theory: 68Credit Points: 68Requirements on Foundation Course:Advanced MathematicsWritten by: Zhang LiqingA.Characteristics and StatusAs the first compulsory basic course of chemistry for majors of chemical engineering and technics, foodscience and engineering,biological engineering,pharmaceutical engineering, materials science andengineering and so on in the institutions of higher learning, inorganic and analytical chemistry is not onlyan important component ofcultivating integral knowledge structureandcapability structure ofengineeringand technicaltalentsofthe said majors,but also afoundationforthe subsequent specializedcoursesB. Teaching TargetsThe course aimstoenable students to master basictheories of substance structure,basicprinciples and application of chemical reaction, basic knowledge of element chemistry,knowledge of and relations among structure, equilibrium, characteristic and application, toresolve general problems of inorganic and analytical chemistry with its theories, to select testapproaches of analytical chemistry, estimate and express test results correctly, and to layfoundation for resolving real problems existing in production and scientific researchesthrough classroom lecturing and close combination with test course of inorganic andanalytical chemistry. Furthermore, through the establishment of strict concept of “quantity",this course also aims to cultivate students'good learning habits, rigorous scholarship,practical and realistic attitude toward science and ability of analyzing and resolving problemsso that students will acquire scientific qualities necessary to scientific and technical personnelgradually.C.Teaching Contents, Basic Requirements and Time AllocationIntroductionTo find out major contents of the course of inorganic and analytical chemistry and theirmutual relations, master learning approaches of this course, understand requirements onlearning this course, learn about targets and characteristics of inorganic and analyticalchemistry, and find out the classification and evolvement of analytical approaches.MajorContentso.1Objectsandcontentsofchemicalresearch-
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 1 Inorganic and Analytical Chemistry S/N: 10421040 Classification: Specialized Basic Course Applicable to: Chemical Engineering and Technics Food Science and Engineering Biological Engineering Pharmaceutical Engineering Materials Science and Engineering Total Hours for Theory: 68 Credit Points: 68 Requirements on Foundation Course: Advanced Mathematics Written by: Zhang Liqing A. Characteristics and Status As the first compulsory basic course of chemistry for majors of chemical engineering and technics, food science and engineering, biological engineering, pharmaceutical engineering, materials science and engineering and so on in the institutions of higher learning, inorganic and analytical chemistry is not only an important component of cultivating integral knowledge structure and capability structure of engineering and technical talents of the said majors, but also a foundation for the subsequent specialized courses. B. Teaching Targets The course aims to enable students to master basic theories of substance structure, basic principles and application of chemical reaction, basic knowledge of element chemistry, knowledge of and relations among structure, equilibrium, characteristic and application, to resolve general problems of inorganic and analytical chemistry with its theories, to select test approaches of analytical chemistry, estimate and express test results correctly, and to lay foundation for resolving real problems existing in production and scientific researches, through classroom lecturing and close combination with test course of inorganic and analytical chemistry. Furthermore, through the establishment of strict concept of “quantity”, this course also aims to cultivate students’ good learning habits, rigorous scholarship, practical and realistic attitude toward science and ability of analyzing and resolving problems, so that students will acquire scientific qualities necessary to scientific and technical personnel gradually. C. Teaching Contents, Basic Requirements and Time Allocation Introduction To find out major contents of the course of inorganic and analytical chemistry and their mutual relations, master learning approaches of this course, understand requirements on learning this course, learn about targets and characteristics of inorganic and analytical chemistry, and find out the classification and evolvement of analytical approaches. Major Contents 0.1 Objects and contents of chemical research
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalyticalChemistry0.2 Major contents of the course of inorganic and analytical chemistry0.3 Learning approaches for the course of inorganic and analytical chemistry0.4Requirementsonlearningthecourseof inorganicand analytical chemistryKeyPoints1. Learning approaches for the course of inorganic and analytical chemistry2.Requirements on learning the course of inorganic and analytical chemistryNodusKnowledge of and relations among structure, equilibrium, characteristic and applicationinteaching contents of inorganic and analytical chemistryChapter 1 Chemometrics and Error and Data ProcessingTo find out basic steps of general analytical course (sampling,pre-processing, measurementand result calculation),to establish the concept of “quantity"clearly, to master basicknowledge of error,causes of error and ways of reduction and avoiding,basic approaches ofdata processing, application of significant data, rejection of doubtful data and correctformulation of analytical results, to learn about concepts of confidence level and confidenceinterval.to master basic concepts of titrimetric analysis.application oftitrimetricanalysis andcalculation methods of titrimetric analysis, and to learn about the evolvement of titrimetricanalysis.Major Contents1.1 Measurement and stoichiometric calculation in chemical reaction1.1.1 Measurement in chemistry and International System of Units1.1.2Introductiontotitrimetric analysis1.1.3Measuringrelations and stoichiometric calculation inchemicalreaction1.2Error and significant figure1.2.1Classification oferror1.2.2 Reduction and avoiding of error1.2.3Formulation of Error1.3Significant figure1.4Processingoftestdata1.4.1 Formulation of testing results1.4.2Confidence level andconfidence intervalKeyPoints:1. Basic steps of general analytical course (sampling, pre-processing, measurement andresultcalculation)2.Basicknowledge oferror3. Causes of error and ways of reduction and avoiding, and basic methods of dataprocessing4.Basic concepts and calculation methods oftitrimetric analysis5. Application of significant data, rejection of doubtful data and correct formulation ofanalytical resultsNodus:1. Rejection of doubtful data and correct formulation of analytical results2.Confidencelevel and confidence interval2
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 2 0.2 Major contents of the course of inorganic and analytical chemistry 0.3 Learning approaches for the course of inorganic and analytical chemistry 0.4 Requirements on learning the course of inorganic and analytical chemistry Key Points: 1. Learning approaches for the course of inorganic and analytical chemistry 2. Requirements on learning the course of inorganic and analytical chemistry Nodus: Knowledge of and relations among structure, equilibrium, characteristic and application in teaching contents of inorganic and analytical chemistry Chapter 1 Chemometrics and Error and Data Processing To find out basic steps of general analytical course (sampling, pre-processing, measurement and result calculation), to establish the concept of “quantity” clearly, to master basic knowledge of error, causes of error and ways of reduction and avoiding, basic approaches of data processing, application of significant data, rejection of doubtful data and correct formulation of analytical results, to learn about concepts of confidence level and confidence interval, to master basic concepts of titrimetric analysis, application of titrimetric analysis and calculation methods of titrimetric analysis, and to learn about the evolvement of titrimetric analysis. Major Contents 1.1 Measurement and stoichiometric calculation in chemical reaction 1.1.1 Measurement in chemistry and International System of Units 1.1.2 Introduction to titrimetric analysis 1.1.3 Measuring relations and stoichiometric calculation in chemical reaction 1.2 Error and significant figure 1.2.1 Classification of error 1.2.2 Reduction and avoiding of error 1.2.3 Formulation of Error 1.3 Significant figure 1.4 Processing of test data 1.4.1 Formulation of testing results 1.4.2 Confidence level and confidence interval Key Points: 1. Basic steps of general analytical course (sampling, pre-processing, measurement and result calculation) 2. Basic knowledge of error 3. Causes of error and ways of reduction and avoiding, and basic methods of data processing 4. Basic concepts and calculation methods of titrimetric analysis 5. Application of significant data, rejection of doubtful data and correct formulation of analytical results Nodus: 1. Rejection of doubtful data and correct formulation of analytical results 2. Confidence level and confidence interval
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalyticalChemistryChapter 2Basic Principles ofChemical ReactionTo learn about concepts of rate equation of chemical reaction (law of mass action) andreaction orders, to master factors of influencing rate of chemical reaction, and to know waysof formulating the influence of concentration, partial pressure, temperature and activatortoward rate of reaction by using concepts of activation energy and molecule.To master rules of chemical equilibrium and equilibrium movement, to be capable ofcalculating the components of equilibrium with equilibrium constant (k°), and to understandthe factorsneeds calculating syntheticallyfor rate of reactionand chemical equilibrium inpractical use.Major Contents:2.1Rateofchemicalreactionanditsaffectingfactors2.1.1 Rate of chemical reaction2.1.2 Affecting factors of rate of chemical reaction2.2 Processing limit of chemical reaction2.2.1Chemical equilibrium and equilibrium constant2.2.2 Movement of chemical equilibriumKeyPoints:1. Rules of chemical equilibrium and equilibrium movement and to be capable ofcalculating the components of equilibrium with equilibrium constant (k°)2.Concepts of rate equation of chemical reaction (lawof mass action)and reaction orders3.Affecting factors of rate ofchemical reactionNodus:1.Formulatingthe influence of concentration,partial pressure,temperature andactivatortoward rate of reaction by using concepts of activation energy and molecule2. Processing and calculation concerned with chemical equilibriumChapter3Acid-base Equilibrium&Acid-base TitrationInthischapterwecanlearnthebasicnotionofthetheoryofBronsted-Lowry,theconceptofthe activity,status of the strong electrolytesolution,understand thecontents and correlativecalculations of dissociationdegreeof weak electrolyte,dilutionlaw,acidity of solution andpH, dissociation equilibrium (include grade dissociation equilibrium), common ion effect,buffer solution and so on, master the principle of method oftitration, titration curve, end pointjudge , end point error and so on ,understand the law of pH changing in various processes ofacid-base titration and the way of choosing the right indicator.MajorContents:3.1Theory of Bronsted-Lowry and acid-base equilibrium3.1.1 Acid-base dissociation equilibrium and constant of dissociation equilibrium3.1.2Relation between Ka &Kb of conjugated pair of acid-base3.2 Moving of acid-base dissociation equilibrium3.2.1 Dilution law3.2.2 Common ion effect,3.2.3 Activity, ionic strength and salt effect3.3Distributing of constituents in acid-base dissociation equilibrium and the calculationoftheconcentration3
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 3 Chapter 2 Basic Principles of Chemical Reaction To learn about concepts of rate equation of chemical reaction (law of mass action) and reaction orders, to master factors of influencing rate of chemical reaction, and to know ways of formulating the influence of concentration, partial pressure, temperature and activator toward rate of reaction by using concepts of activation energy and molecule. To master rules of chemical equilibrium and equilibrium movement, to be capable of calculating the components of equilibrium with equilibrium constant (Kș ), and to understand the factors needs calculating synthetically for rate of reaction and chemical equilibrium in practical use. Major Contents: 2.1 Rate of chemical reaction and its affecting factors 2.1.1 Rate of chemical reaction 2.1.2 Affecting factors of rate of chemical reaction 2.2 Processing limit of chemical reaction 2.2.1 Chemical equilibrium and equilibrium constant 2.2.2 Movement of chemical equilibrium Key Points: 1. Rules of chemical equilibrium and equilibrium movement and to be capable of calculating the components of equilibrium with equilibrium constant (Kș ) 2. Concepts of rate equation of chemical reaction (law of mass action) and reaction orders 3. Affecting factors of rate of chemical reaction Nodus: 1. Formulating the influence of concentration, partial pressure, temperature and activator toward rate of reaction by using concepts of activation energy and molecule 2. Processing and calculation concerned with chemical equilibrium Chapter 3 Acid-base Equilibrium & Acid-base Titration In this chapter we can learn the basic notion of the theory of Brønsted-Lowry, the concept of the activity, status of the strong electrolyte solution, understand the contents and correlative calculations of dissociation degree of weak electrolyte, dilution law, acidity of solution and pH, dissociation equilibrium (include grade dissociation equilibrium ) , common ion effect, buffer solution and so on, master the principle of method of titration, titration curve, end point judge , end point error and so on ,understand the law of pH changing in various processes of acid-base titration and the way of choosing the right indicator. Major Contents: 3.1 Theory of Brønsted-Lowry and acid-base equilibrium 3.1.1 Acid-base dissociation equilibrium and constant of dissociation equilibrium 3.1.2 Relation between Ka & Kb of conjugated pair of acid-base 3.2 Moving of acid-base dissociation equilibrium 3.2.1 Dilution law 3.2.2 Common ion effect, 3.2.3 Activity, ionic strength and salt effect 3.3 Distributing of constituents in acid-base dissociation equilibrium and the calculation of the concentration
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical Chemistry3.3.1Distribution factoranddistributioncurve3.3.2 Calculation about equilibrium concentrations of constituents3.4Calculation of solution acidity3.4.1Confirmation of proton balance equation3.4.2Calculationofacidityofweakmono-acid(alkali)3.4.3 Calculation of acidity of ampholyteric compound solution3.5 Control and detection of the solution acidity3.5.1 Acid-base buffer solution3.5.2 Acid-base indicator3.6Acid-basetitration3.6.1 Strong alkali (acid) titrate strong alkali(acid)3.6.2 Strong alkali (acid) titrate weak mono-acid (alkali)3.6.3 Titration of polyatomic acid and mixed acid3.6.4Applicationofacid-basetitrationKey Points:1. The contents and correlative calculations of dissociation degree of weak electrolytedilution law, acidity of solution and pH, dissociation equilibrium, common ion effect,buffersolutionand soon2. Basic concepts of acid-base titration (titration, end point, stoichiometric point, indicator,standard solution, standard substance)3. Principle of acid-base titration analysis, titrate curve, end point judgement, end pointerror4.Application of acid-base titration and calculation oftitration result.Nodus:1. The law of pH changing in various processes of acid-base titration and the way ofchoosing the right indicator.2.Distributionfactoranddistributioncurve,confirmationof protonbalanceequation3. Calculation of acidity of ampholyteric compound solution, and titration of the mixedacid and polyatomic acidChapter 4Precipitation-dissolution Equilibrium &Precipitation Testing MethodIn this chapter we can learn contents and relative calculations about precipitation-dissolutionequilibrium,solubility product principle and so on, learn how to judge whether precipitationor dissolution will come out with the solubility product principle, master calculation offractional precipitation,learn the principleof precipitation titration analysis,end point judge,understand the applicationof precipitationtitration analysis and calculation oftitrationresultlearn the feature of gravimetric method and its principle and process.Major Contents:4.1 Formation of precipitation and dissolution equilibrium4.1.1 Solubility product principle and solubility4.1.2Dominant factor for solubility4.2Solutionofprecipitation,fractionalprecipitationandinversionofprecipitation4.2.1Fractional precipitation4.2.2 Application of fractional precipitation4.2.3 Inversion of precipitation4
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 4 3.3.1 Distribution factor and distribution curve 3.3.2 Calculation about equilibrium concentrations of constituents 3.4 Calculation of solution acidity 3.4.1 Confirmation of proton balance equation 3.4.2 Calculation of acidity of weak mono-acid (alkali) 3.4.3 Calculation of acidity of ampholyteric compound solution 3.5 Control and detection of the solution acidity 3.5.1 Acid-base buffer solution 3.5.2 Acid-base indicator 3.6 Acid-base titration 3.6.1 Strong alkali (acid) titrate strong alkali(acid) 3.6.2 Strong alkali (acid) titrate weak mono-acid (alkali) 3.6.3 Titration of polyatomic acid and mixed acid 3.6.4 Application of acid-base titration Key Points: 1. The contents and correlative calculations of dissociation degree of weak electrolyte, dilution law, acidity of solution and pH, dissociation equilibrium, common ion effect, buffer solution and so on. 2. Basic concepts of acid-base titration (titration, end point, stoichiometric point, indicator, standard solution, standard substance) 3. Principle of acid-base titration analysis, titrate curve, end point judgement, end point error 4. Application of acid-base titration and calculation of titration result. Nodus: 1. The law of pH changing in various processes of acid-base titration and the way of choosing the right indicator. 2. Distribution factor and distribution curve, confirmation of proton balance equation 3. Calculation of acidity of ampholyteric compound solution, and titration of the mixed acid and polyatomic acid Chapter 4 Precipitation-dissolution Equilibrium & Precipitation Testing Method In this chapter we can learn contents and relative calculations about precipitation-dissolution equilibrium , solubility product principle and so on, learn how to judge whether precipitation or dissolution will come out with the solubility product principle, master calculation of fractional precipitation, learn the principle of precipitation titration analysis, end point judge, understand the application of precipitation titration analysis and calculation of titration result, learn the feature of gravimetric method and its principle and process. Major Contents: 4.1 Formation of precipitation and dissolution equilibrium 4.1.1 Solubility product principle and solubility 4.1.2 Dominant factor for solubility 4.2 Solution of precipitation ,fractional precipitation and inversion of precipitation 4.2.1 Fractional precipitation 4.2.2 Application of fractional precipitation 4.2.3 Inversion of precipitation
Syllabus of Zhejiang University of Science and TechnologyInorganicandAnalytical Chemistry4.3 Formation of precipitation4.3.1 Kinds of precipitation4.3.2 Formation of precipitation4.3.3Factorfor purityof precipitation4.3.4Measureforgoodpureprecipitation4.4 Precipitation testing method4.4.1Gravimetric method4.4.2Precipitation titration analysisKeyPoints:1. Precipitation-dissolution equilibrium, solubility product principle2. Judge whether precipitation or dissolution will come out with the solubility productprinciple, feature of gravimetric method and its principle and process.3.Application of precipitation titration analysis and calculation oftitration resultNodus:1.Fractional precipitation and relative calculation2.Principle of precipitation titration analysis and end point judge3.Application of precipitation titration analysis and calculation of titration resultChapter5RedoxEquilibriumandRedoxTitrationIn this chapter we can learn contents and relative calculations about redox equilibrium,electrode potential and so on, understand the principle of redox titration, learn the way ofchoosing the right condition for redox titration, master application of redox titration analysisand calculation of titrationresultMajor Contents:5.1 Redox reaction and electrode potential5.1.1Oxidation number5.1.2 Balancing of equation of redox reaction5.2.1 Primary battery5.2.2 Electrode potential5.2.3 Standard electrode potential5.2.4Factorforelectrodepotential5.2.5 Conditional potential5.3 Applicationofelectrodepotential5.3.1 Calculation of electromotive force of primary battery5.3.2 Judge the direction of redox reaction5.3.3Judgethelimitationof redoxreaction5.3.4Calculationofrelativeequilibriumconstant5.3.5Chart of standard electrodepotential ofelements5.4 Reaction rateofredoxreaction5.5 Redoxtitration5.5.1Redox titrate curve5.5.2Detectionoftheendofredoxtitration5.5.3 Redox titration analysis5.5.4 Calculation of redox titration resultKey Points:5
Syllabus of Zhejiang University of Science and Technology Inorganic and Analytical Chemistry 5 4.3 Formation of precipitation 4.3.1 Kinds of precipitation 4.3.2 Formation of precipitation 4.3.3 Factor for purity of precipitation 4.3.4 Measure for good pure precipitation 4.4 Precipitation testing method 4.4.1 Gravimetric method 4.4.2 Precipitation titration analysis Key Points: 1. Precipitation-dissolution equilibrium, solubility product principle 2. Judge whether precipitation or dissolution will come out with the solubility product principle, feature of gravimetric method and its principle and process. 3. Application of precipitation titration analysis and calculation of titration result Nodus: 1. Fractional precipitation and relative calculation 2. Principle of precipitation titration analysis and end point judge 3. Application of precipitation titration analysis and calculation of titration result Chapter 5 Redox Equilibrium and Redox Titration In this chapter we can learn contents and relative calculations about redox equilibrium, electrode potential and so on, understand the principle of redox titration, learn the way of choosing the right condition for redox titration, master application of redox titration analysis and calculation of titration result. Major Contents : 5.1 Redox reaction and electrode potential 5.1.1 Oxidation number 5.1.2 Balancing of equation of redox reaction 5.2.1 Primary battery 5.2.2 Electrode potential 5.2.3 Standard electrode potential 5.2.4 Factor for electrode potential 5.2.5 Conditional potential 5.3 Application of electrode potential 5.3.1 Calculation of electromotive force of primary battery 5.3.2 Judge the direction of redox reaction 5.3.3 Judge the limitation of redox reaction 5.3.4 Calculation of relative equilibrium constant 5.3.5 Chart of standard electrode potential of elements 5.4 Reaction rate of redox reaction 5.5 Redox titration 5.5.1 Redox titrate curve 5.5.2 Detection of the end of redox titration 5.5.3 Redox titration analysis 5.5.4 Calculation of redox titration result Key Points: