试题库三：完成反应式 1.(CH)2C=CHCH3-HBr_ 2. CHOCH-CH+HBr- 3.CH3CH2CH=CH2 -CH3CH2CH2CH2OH 4.CHCH-C出微 5.(CHhC-CHCH:CH②zn粉，H2o ①03 6.CH2=CHCH2OH CICH2CHCHOH OH 7.CHCH2CHC≡CH+HCI(过量) 8.CHCH2C≡CH+HBr(过量)→ 9.CH3CH2C=CCH3 KMnO4H A 10.CHCH-C-CCH +H2O 11.CH2=CHCH=CH2CH2=CHCHO 12. ☒丰B 13. +c,超 14. +Ch→ 15. Br 16. 17. c 003 18. CtC 19 A CH-CH KMnQ 20. ○ych02 ②H20△ 21. ○+CH,Ch_Aa 1
1 试题库三：完成反应式 1． 2． 3．CH3CH2CH=CH2 → CH3CH2CH2CH2OH 4．CH3CH=CH2 5．(CH3)2C=CHCH2CH3 6．CH2=CHCH2OH → 7．CH3CH2CH2C≡CH + HCl（过量）→ 8．CH3CH2C≡CH + HBr（过量）→ 9．CH3CH2C≡CCH3 + KMnO4 10．CH3CH2C≡CCH3 + H2O 11．CH2=CHCH= CH2 + CH2=CHCHO → 12． 13． 14． 15． 16． 17． 18． 19． 20． 21． (CH3 )2C=CHCH3 HBr ① ② O3 Zn粉, H2O ClCH2CHCH2OH OH △ H + H2SO4 HgSO4 CH3 + HBr + Cl2 高温 + Cl2 CH2CH3 Br + 2 CH(CH 3 )2 Cl + 2 高温 CH3 ① O3 ② H2O △ CH3 ① ② H2O △ H2SO4 + CH2Cl2 AlCl3 ①B2H6 ②H2O2 ① O3 ②H2O △ CH3 CH=CH2 CH=CH2 KMnO4 CH3OCH=CH2+ HBr
22. C.o 23. Co 品 ◇vo 25. +KMnO, 26. c+cH2+ch→ 27.CoHCHCI-M o 28.CH2=CHCH2Br NaOC2H5- 29. 0告 30. O+晚→ CH2=CHCHO 31. 器 2.品*0✉ .d”o 34.Go叫 B 35. ○-BrKOL 36.CH2=CHCH-CI CH2=CHCH2CN 37. (CH3)CCl+NaOH Ho 38. (CH3)CHCH2CH2OH+HBr- 39.○oH+Ha2C 40.-OH_ 41.8o046+mct量) 42.go一 2
2 22． 23． 24． 25． 26． 27． 28． 29． 30． 31． 32． 33． 34． 35． 36．CH2=CHCH2Cl CH2=CHCH2CN 37． (CH3)3CCl + NaOH 38． (CH3)2CHCH2CH2OH + HBr 39． 40． 41． 42． + CH3 HNO3 + KMnO4 H + △ CH=CH2 + Cl2 C6H5CH2Cl Mg CO2 H + H2O CH2=CHCH2Br + NaOC2H5 CH=CHBr CH2Br AgNO3 室温 + 乙醇 + Br2 KOH-乙醇 △ CH2=CHCHO CH2Cl Cl H2O NaOH , △ H2O CH3 Cl OH - + SN2历程 H2O CH3 OH - + Cl SN1历程 Br KOH-乙醇 H2O OH + HCl 无水ZnCl2 + HI OCH3 CH2CH2OCH3 （过量） + HI O CH3 （过量） Fe Br SO3H 2 OH AlCl3 CH3 SO3/ H2SO4 CH3 Br EtONa
43.(CH3)CHBr NaOC2Hs 44. 45. HIO4CH3COOH+CH3CH2CHO 46. CHa HIO4_CH3COCH2CH2CH2CHO 47.○+B2→ OH 48.CHCH,CHCHCH CH OH (分子内戬水) 49.CH3COCH-CH3+H2N-OH- 50.Cl3CCHO+H20→ 51.Hc《cHo+Kh04→ 52.CH3 CH2CHO稀NOH, 53.C6HsCOCHs+C6HsMgBr- 9 54. 5.○=0+HNOH 56.(CH5CCHO浓NaOH 57.○0+(CH2ccH02kC 58. s9.了ao曾 60. ol 61. c +c 62.CH2=CHCH2CH2COCH3 HCI- 63.CHsCHO CHsCOCH 64.CHgCOCHCOC. CHa 65.CHaCOCHCO 2CHs NaoH CH2C02CH3△ 66. 67. oOt 3
3 43．(CH3)2CHBr + NaOC2H5 44． 45． CH3COOH + CH3CH2CHO 46． CH3COCH2CH2CH2CHO 47． 48． 49．CH3COCH2CH3 + H2N-OH → 50． Cl3CCHO + H2O → 51． 52．CH3CH2CHO 53．C6H5COCH3 + C6H5MgBr → 54． 55． 56．(CH3)3CCHO 57． 58． 59． 60． 61． 62．CH2=CHCH2CH2COCH3 + HCl → 63．C6H5CHO + CH3COCH3 → 64． 65． 66． 67． CH3CH2CH2CH2CHCH3 OH KMnO4 OH - HIO4 HIO4 CH3 OH + Br2 CH3CH2CH2CHCH2CH3 OH 浓 H2SO4 △ （分子内脱水） H3C CHO + KMnO4 稀NaOH H2O H + O + H2NNHC6H5 浓NaOH O + (CH3 )2C(CH2OH)2 无水HCl O + Na2CrO7 △ H + KMnO4 CHO 室温 CCH3 O Cl2 H2O OH - , CCH3 O Cl + 2 H + H H2O CH3COCHCO 2C2H5 + CH3 OH - 稀 , ① △ ② , CH3COCHCO 2CH3 CH2CO2CH3 △ 浓 NaOH CH3CH2CHCOOH OH △ H + 稀 △ CO2CH3 COCH3 O + H2NOH
68. 70. CH3CHCH2COOH△ OH 0 71. HgC CHa 72. OH 74. 75. 76.0.8 77. CHgCH2COOH Cl2-P 78.1 ①c 79.(CH3)CHOH +HaCCOCI- 80.HOCH2CH2COOH LiA 81.NCCH-CH-CN +H2O Naol 比 82.1 CH3 83.CH3COCI+ 84.(CH0020+《-oH→ 85.CH3CH2COO C2Hs NaOF 86.CH3COOC2Hs+CH3CH2CH2OH-
4 68． 69． 70． 71． 72． 73． 74． 75． 76． 77． 78． 79． 80．HOCH2CH2COOH 81．NCCH2CH2CN + H2O 82． 83．CH3COCl + 84． 85．CH3CH2COO C2H5 86．CH3COOC2H5 + CH3CH2CH2OH → △ HO2CCH2COCCOOH CH3 CH3 NaOH H2O △ CH3CH2CHCOOH Cl - △ CH3CHCH2COOH OH NaOH H2O △ O - O H3C 稀 △ CH3CH2CCOOH OH CH3 H2SO4 稀 △ CH3CH2COCO2H H2SO4 CH3CHCOCO2H CH3 △ △ COOH COOH COOH H + ① ② NaOH△ O O , , △ CH3CH2COOH Cl + 2 P Na - 2Cr2O7 H2O (CH3 )2CHOH + H3C COCl LiAlH4 NaOH H + CH2COOH CH2COOH △ Ba(OH)2 CH3 无水AlCl3 (CH3CO)2O + OH NaOEt
87.CH;CH(COOH)2→ 8.○-c0oH+a一 89.2○c00H+H0CH20H20H→ 90. cooma 91.H0ooH+○oH→ 92.CH2CHzCOOC2Hs NaO CH2CH2COOC2Hs 93. CONH2 O 94.(C2Hs)3N+CH3CHBrCH3- 95.[(CH3)3NCH2CH2CH2CH3]*Cl+NaOH 96.CH3CH2COCI+HcNHCH3_ 97.+0:一 98.CHCHCOOCH CH-CH-COOCHs NocH,？ CH.CHBE 99. CHCICICN WO 100, H202 CHaSCH3-30%HAe ？ 101. 102. 0 KMnO/H* 103.CH;CH2CHO- A 104. ° H 105. -CH+HsCH2 )3SH HCI 106.CH,CH;OH/O CH.CHO ②Mg/乙醚 ②H0 5
5 87．CH3CH(COOH)2 88． 89． 90． 91． 92． 93． 94．(C2H5)3N + CH3CHBrCH3 → 95． [(CH3)3NCH2CH2CH2CH3] +Cl- + NaOH → 96．CH3CH2COCl + 97． 98． 99． 100． 101． 102． 103． 104． 105． 106． △ COOH + HCl 2 COOH + HOCH2CH2OH COOH LiAlH4 HCOOH + OH CH2CH2COOC2H5 CH2CH2COOC2H5 NaOEt N CONH2 OH - △ H3C NHCH3 N(C2H5 )2 + HNO2 O H CHO ？ 3C 浓碱 CH3SCH3 ？ H2O2 30%HAc △ ？ N KMnO4 / H + NaOC2H5 △ ？ ？ CH2CH2COOC2H5 CH2CH2COOC2H5 CH3CH2Br ？ ① NaOH / H2O ② H + / H2O ？ △ H + / H2O △ ？ CH2CH2CH2CN OH H + CH3CH2CHO OH - △ NaBH4 O HCN H2O H + CHO + HS(CH2 )3SH HCl CH3CH2OH ① NaBr / H2SO4 ② Mg / 乙醚 ① CH3CHO ② H2O ? ? ? ① Na2Cr2O7 ② HOCH2CH2OH