脉冲傅立叶变换核磁共振谱仪 Normal rf pulses are square shaped (in the time domain), their excitation profile(in the quare Sinc frequency domain) is given by A for(0<t<T) A[sin(ot)/(ot)] ts fourier transform. the sinc function(approximation forβ180°) he excitation band width is proportional to the reciprocal of the pulse duration, pulses V(HZ must be short enough to keep the wiggles outside the range of interest. THNMR YAN
THNMR YAN 脉冲傅立叶变换核磁共振谱仪 Normal rf pulses are square shaped (in the time domain), their excitation profile (in the frequency domain) is given by its FOURIER transform, the sinc function (approximation for b«180°). The excitation band width is proportional to the reciprocal of the pulse duration, pulses must be short enough to keep the "wiggles" outside the range of interest
Magnet Most magnets are of the superconducting type N2 reservoir Vacuum He Reservoir Vacuum sUperconducting Solenoid Liquid Helium Liquid Nitrogen Container Support Superconducting Coil 2 THNMR YAN
Magnet Most magnets are of the superconducting type. THNMR YAN
Why Magnet is so Important Boltzmann statistics N/N+=e-E/kT=e-y B/kT For 300 K one gets for H a population difference n--N of B △N 1.4T 60 MHZ 9.9·10 117T500MHZ 77·10 THNMR AN
Why Magnet is so Important Boltzmann Statistics N- /N+ = e-E/kT = e-gB/kT . For 300 K one gets for 1H a population difference N- -N+ of B w DN 1.4T 60 MHz 9.9·10-6 11.7T 500 MHz 77 ·10-6 THNMR YAN
Why Magnet is so Important 费 Resolution~B 豪 Sensitivity~(B0)32 豪 Allignment~(B1)2 e Relaxation (complex)
Why Magnet is so Important Resolution ~ B0 Sensitivity ~ (B0 ) 3/2 Allignment ~ (B0 ) 2 Relaxation ~ (complex)
400 MHz Nuclei (ppm) A 1.89 62.1 2.0 1.9 B 2.00 2.0 100 MHz Interaction J (Hz AB BC 2.1 2.0 9 2 THNMR YAN
THNMR YAN Nuclei (ppm) A 1.89 B 2.00 C 2.08 Interaction J (Hz) AB 4 BC 8