有机化学 Organic chemistry 2010 For Undergraduates in biological science 王俊儒张继文袁茂森 应用化学系416,417室 87092187(0) By Junru Wang Email:wangjr07@163.com 西北农林科技大学理学院
Organic Chemistry,6th Edition L.G.Wade,Jr. Chapter 6 Stereochemistry :
Content Molecular Chirality Chiral carbon Absolute and Relative Configuration Stereoisomers without chiral carbons Properties of Enantiomers Diastereomers Resolution of Enantiomers
Key Notes Stereochemistry Chiral enantiomers Chirality Chiral center Optical rotations R/S,D/L Diastereomers meso forms Resolution of enantiomers
Stereoisomers Same bonding sequence. Different arrangement in space. Example:HOOC-CH=CH-COOH has two geometric(cis-trans)isomers: OH HO- OH HO-( fumaric acid,mp 287 C maleic acid,mp 138C essential metabolite toxic irritant