Chapter 7Selective oxidation of hydrocarbon
Selective oxidation of hydrocarbon Chapter 7
Main contentsIntroductionHomogeneous catalytic oxidationHeterogeneous catalytic oxidationEthylene oxide preparation by ethene epoxidationAcrylonitrile preparation by propene ammoxidationPhthalic anhydride preparation by aromatic oxidation
Main contents Ethylene oxide preparation by ethene epoxidation Heterogeneous catalytic oxidation Homogeneous catalytic oxidation Introduction Acrylonitrile preparation by propene ammoxidation Phthalic anhydride preparation by aromatic oxidation
7.1IntroductionA series of important products, such as alcohols.aldehydes,carboxylic acids,ketones,and esters,canbe obtained byoxidationreactions of hvdrocarbonsThese products are an important organic chemicalraw materials andintermediates, and some areimportant monomers of three synthetic materials
7.1 Introduction A series of important products, such as alcohols, aldehydes, carboxylic acids, ketones, and esters, can be obtained by oxidation reactions of hydrocarbons. These products are an important organic chemical raw materials and intermediates, and some are important monomers of three synthetic materials
Con.%Selv.%AirHC-CH98750HC- CH,OmCH3Air79100CH3儿0
Con.% Selv.% Air HC HC CH2 CH2 O 98 75 CH3 CH3 Air C C O O O 100 79
NH3,AirC= C-CC = C-CNOxygenC=COxygenC=C-C0Oxygen11C=CC- C-H
C C C NH3 ,Air C C CN C C Oxygen C C O C C C Oxygen C C C O C C Oxygen O Ｃ- C-H