(42)、偏离最可儿分布的几率函数(44)二、二项式分布三、正态曲线(46)(50)S分子配分函数的计算量子态求和.(50)一、三维平动子的9二、刚性哑铃转子的9(53)三、谐振子的4(55)(56)四、多原子分子的..和..............+.+五、分子中电子运动的9(61)(62)六、核自旋的9$5绝对炳…·(64)一、量热摘(64)二、统计摘(66).....三、统计摘与量热摘的比较(71)习题·第三章系综统计法(79).3
一、偏离最可儿分布的几率函数 ·················· . (42) 二、二项式分布 ··············，·。······················. (44) 三、正态曲线 ····································，·。···. (刁6) 虽4 分子配分函数的计算— 量子态求和”，·”··“··一 (50) 一、三维平动子的 q，·······························，·. (50) 二、刚性哑铃转子的夕，······························”·. (53) 三、谐振子的、，·················。··········。···········一 (55) 四、多原子分子的 q。和 q，·················，·········. (56) 五、分子中电子运动的q，·········，········。······，·. (61) 六、核自旋的q。·······································. (62) ;5 绝对嫡···············，·····················，·············. (64) 一、量热嫡 ·············.，’·······················. (64) 二、统计嫡 ··，·········，····················，···········. (66) 三、统计墒与量热嫡的比较 ·················，···，··. (71) 习 题 .第三章 系综统计法 (79)
81系综的概念(79)$2正则系综(81)(82)一、正则分布函数.(85)二、正则配分函数(87)三、状态性质的正则平均(89)四、正则系综的能量涨落83巨正则系综(92)(93)一、巨正则分布函数(96)二、巨正则配分函数：三、状态函数的巨正则平均(98)(101)四、巨正测系综的涨落(107)S4几个有关问题的讨论(107)一、状态性质偏离平均值的几率函数(108)三、热力学关系式的统计诠释(113)三、系综统计与破尔兹曼统计的比较(115)四、其他系综习题4
荟1 系综的慨念······.!’二，’········. ”·. ，’. (79) 荟2 正则系综········，··.，·······。·.”···.·············一 (81) 一、正则分布函数 二，······················一 、···. (82) 二、正则配分函数 ·.”······················.”. (85) 三、状态性质的正则平均 ·························”··一 (37) 四、正则系综的能量涨落 ························”·. (89) 互3 巨正则系综··········，····”······················”，···. (92) 一 巨正则分布函数 ·······。，·················.·····，·. (93) 二、巨正则配分函数 ··················，··，·············一 (96) 三、状态函数的巨正则平均 .’·····················。··. (98) 四、巨正则系综的涨落·.‘·······.·············. (101) 互4 几个有关问题的讨论···············.，’···。，·. (107) 一、状态性质偏离平均值的几率函数 ·········. (J07) 二、热力学关系式的统计淦释 ······一 ，’···. (108) 三、系综统汁与玻尔该曼流墓{的比较 ······”··。一 (113) 四、其1也系综 ·············。········。············。···。·. (115) 习 题
(120)第四章经典统计系综SL(120)保守力学系运动方程(120)一、正则运动方程二、相体积与相几率密度(121).三、刘维定理.(124)(128)S2经典微正则系综(128)一、微正则分布函数(133)二、状态函数的微正则平均”三、微正则分函·(135)S3吉布斯正则系综(136)(137)一、相空阀正则级合-(138)二，吉布期正赔分布函数·(141)三、内能与缩平均4分子配分函数的计算一一相空间积分(142)(142)一双原子分享的和二、刚体转动的4(145)..5
第四章 经典统计系综 (120) 圣I ;2 互3 互4 保守力学系运动方程 ·········。···············.‘一 (120) 一、正则运动方程，。··，···············.。········. (」20) 二、相体积与相几率密度··················，········. (12J) 三、刘维定理···························，···，···。·······，·. (124) 经典微正则系综 ·······················。············. (128) 一、微正则分布函数···········，··。··········。······. (128) 二、状态函数的微正则平均·····，·········.山··. (13) 三 、微正则配分函戮.··介········.~···········。··. 〔135) 吉布斯正则系综 ·‘·。············，··················. (呈3C) 一、才几空流正则组合······，············，····。，···. ‘二37) 二、吉布斯正则分布勇赞····················，·一 ”一 ‘138) 三、内能与摘平均···毛······，-····。··················。. (1封) 分子配分函数的计算一一 札空问积分 ········，八一 (ldZ) 一、双原子另可二的9‘、9，不一介叮: ·。···········。·········。. (142) 二、刚体转动的叮r ··，·········。···············。····. (145) ，5
三、分子内旋转的(152)习题第五章简单体系(159)(159)$1理想气体(159)一、化学位及其标准态(161)二、气体的热容(166)三、多组份气体的及三(168)四、混合摘(170)五、吉布斯伴谬，(172)S2金属晶体.一、晶体的爱因斯坦模型(173).二、金属热容..(176)(178)三晶体与其蒸汽的平衡83理想固溶体(179)(180)一、二元固溶体的正则配分函数.二、固溶体混合摘·(184).6
三、分子内旋转的如 习 题 (152) 第五章 简单体系 (159) ;l ;2 ;3 理想气体 ·············································. (159) 一、化学位及其标准态·。········，···················. (159) 二、气体的热容··································，····. (161) 三、多组份气体的 甲及 三 ························. (166) 四、混合嫡········，·.································，··一 (168) 五、吉布斯佯谬·······················，···············. (J70) 金属晶体 ················。····················。··。····. (172) 一、晶体的爱因斯坦模型，·············，·············一 (173) 二、金属热容······························，·············。. (176) 三、晶体与其蒸汽 冲乎衡···························. (178) 理想固溶体 ·········································，. (!79) 一、二元固溶体的正则配分函数一 补····，······. (180) 二、固溶体混合嫡·······················，···········。. (184)
三、固溶体的巨正则配分函数(186)$4气固吸附(188)(189)一、朗格谬尔吸附方程二、吸附摘(192)三、多层吸附的B.E.T公式(195)85化学平衡常数(202)、K，的统计表达式(203)二、化学反应的涨落(206)三、同位素交换反应(208)习题(215)第六章量子气体.$1(215)三种能量分布律的比较(215)-、B-E分布二.F-D分布.....(217)....(217)三、与M一B分布比较(221)82量子气体巨正则配分函数.7
三、固溶体的巨正则配分函数·····，········，······ ·一 (186) 圣4 气固吸附 ·。············，················。·············. (188) 一、朗格谬尔吸附方程······························，··. (189) 二、吸附嫡························，···············。····. (192) 三、多层吸附的 刀.E.望公式 ·······，·······，·····. (195) 虽5 化学平衡常数 ·······································. (202) 一二、It’，的统计表达式 ··················，···········. (203) 二、化学反应的涨落·············，·········，·········. (206) 三、同位素交换反应·································. (208) 习 题 第六章 里子气体 (215) ;1 虽2 三种能量分布律的比较····························，·. (215) 一、刀一E分布 ···························，···········. (215) 二、F一D分布 ·······································，··. (217) 三、与 M一刀分布比较 ·····························一 (217) 量子气体 巨正则配分 函数 ························. (221)