Pepper Extract-Power of MS Resolution and Mass Accuracy x101+ESI TIC Scan Frag-120.0V Pest MX_20 Pepper_10ppb in 1_3 water.d 9 城 0.5 1 29 4.5 55 7 ×101 +ESI EIC(489.0435)Scan Frag=120.0V Pest MX_20 Pepper_10ppb in 1 3 water.d 6 5 3 0 03 1.522.5 3.54 4 55.5 66.57 7.5 8 ns (%Vs. tion Time (min) Pesticide Analysis with New Agilent Jet Agilent Technologies Page 11 14.200
Pepper Extract – Power of MS Resolution and Mass Accuracy Pesticide Analysis with New Agilent Jet Stream Technology Page 11 April 14, 2009
Extracted lon Chromatogram m/z 202.0433+0.002 of Lettuce Extract x10 2+ESI TIC Scan Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 water.d 09 0.8 06 0.3 2 0.1 10 ESIEIC2020433) 65 6555 415415215115 Thiabendazole at 0.1 ppb 4.768 A 6146 15 25 3544.555.566.57758859g51010.511115 Counts(%)vs.Acquisition Time(min) Pesticide Analysis with New Agilent Jet Page 12 Agilent Technologies seA物2
Extracted Ion Chromatogram m/z 202.0433±0.002 of Lettuce Extract 2 x10 0 7 0.8 0.9 1 +ESI TIC Scan Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 water.d 1 1 of Lettuce Extract 0.3 0.4 0.5 0.6 0.7 0 0.1 0.2 -2 x10 6 5 7 +ESI EIC(202.0433) Scan Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 water.d Smooth 1 1.441 1 3.5 4 4.5 5 5.5 6 6.5 0.725 Thiabendazole at 0.1 ppb 0 0.5 1 1.5 2 2.5 3 2.581 3.323 4.768 6.146 Thiabendazole at 0.1 ppb 0 Counts (%) vs. Acquisition Time (min) 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 Pesticide Analysis with New Agilent Jet Stream Technology Page 12 April 14, 2009
Mass Spectrum of Chromatographic Peak for Thiabendazole x105+ESI Scan(2.501-2.660 min,13 scans)Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 water.d Subtract 390.1763 219 1.6 7672738 193.0859 300.2019 234.5509 722.4532 150 200 250 300 350 400 450500 550600 650 700750800 8509009501000 Co unts vS.Mass-10- Charge (m/z) Pesticide Analysis with New Agilent Jet Agilent Technologies Page 13 14.200
Mass Spectrum of Chromatographic Peak for Thiabendazole 5 x10 2 2.1 2.2 +ESI Scan (2.501-2.660 min, 13 scans) Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 water.d Subtract 390.1763 1 4 1.5 1.6 1.7 1.8 1.9 0.9 1 1.1 1.2 1.3 1.4 767.2738 193.0859 300 2019 0.3 0.4 0.5 0.6 0.7 0.8 300.2019 0 0.1 0.2 234.5509 722.4532 Counts vs. Mass-to-Charge (m/z) 100 150 200 250 300 350 400 450 500 550 600 650 700 750 800 850 900 950 1000 Pesticide Analysis with New Agilent Jet Stream Technology Page 13 April 14, 2009
Spectrum of Thiabendazole at 0.1 ppb in Extracted Pepper x103+ESI Scan(2.501-2.660 min,13 scans)Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 ater.d Subtract 202.03 1.3 1.25 1.2 Resolving power=15,000 05 201.1091 0.9 0.85 4150156155 204.1217 0.05 20 201 201.8 202.2 202.4 202.6 2028 203.2 203 203.6203.8 204 2042 04. 204.6204.8205205.2205.4205.6 Charge (m/z) Pesticide Analysis with New Agilent Jet Agilent Technologies Page 14 Ar 4009
Spectrum of Thiabendazole at 0.1 ppb in Extracted Pepper x10 3 1.35 1.4 1.45 +ESI Scan (2.501-2.660 min, 13 scans) Frag=120.0V Pest MX_20 Lettuce_01 ppb in 1_3 ater.d Subtract 202.0431 (M+H)+ Pepper 1 1.05 1.1 1.15 1.2 1.25 1.3 201 1091 Resolving power= 15,000 0.65 0.7 0.75 0.8 0.85 0.9 0.95 201.1091 0 3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 204.1217 0 0.05 0.1 0.15 0.2 0.25 0.3 201 201 2 201 4 201 6 201 8 202 202 2 202 4 202 6 202 8 203 203 2 203 4 203 6 203 8 204 204 2 204 4 204 6 204 8 205 205 2 205 4 205 6 Counts vs. Mass-to-Charge (m/z) 201 201.2 201.4 201.6 201.8 202 202.2 202.4 202.6 202.8 203 203.2 203.4 203.6 203.8 204 204.2 204.4 204.6 204.8 205 205.2 205.4 205.6 Pesticide Analysis with New Agilent Jet Stream Technology Page 14 April 14, 2009
Calculated Formula of Thiabendazole at 0.1 ppb in Extracted Pepper MS Formula Results:+Scan (2.501-2.660 min)Sub m/z lon Formula Abundance 202043 (M+H+ C10H8N3S 14154 Best Formula (M) lon Formula Score Cross Scote Calc m/z Diff [ppm)Mass Match Abund Match Spacing Match C10H7 N3S C10H8N3S 9596 2020433 13 99.31 94.72 9032 Isulupe W/c Cale e Diff (ppm) 6.84 84.73 202.0431 202.0433 1.28 2 9.16 10.84 203.0447 203.0459 587 3 4.01 4.43 204.0382 204.0405 11.11 Best Formula (M) lon Formula Score Cross Score Calc m/z Diff (ppm) Mass Match Abund Match Spacing Match C6H7N305 C6H8N305 59.68 2020458 13.75 45.89 81.12 61.54 C12H8CIN C12H9CIN 59.62 2020418 6.36 84.62 0.31 8079 C4H12QN30. C4H13 CIN3 02S 55.62 2020412 -9.62 68.31 0.02 96.94 C9H12CNS C9H13CNS 51.04 202045 104 64.03 0.05 86.24 C13H3N3 C13H4N3 48.82 20204 15.46 37.32 64.34 5317 Chromatogram Results MS Formula Results:Scan (2501-2.660 min]Sub Pesticide Analysis with New Agilent Jet AgilentTechnologies Stream Technology Page15 April 14.2009
Calculated Formula of Thiabendazole at 0.1 ppb in Extracted Pepper Extracted Pepper Pesticide Analysis with New Agilent Jet Stream Technology Page 15 April 14, 2009