续表1026/(m3.mo1-)a/(V-m4.mol-2)名称化学式0.19942.925C,H,CO,C,Hs异丁酸乙醛0.14242.311CHu环己烷0.1669二异丙茶2.344(CHz20.18312.763(C,Hs),N三乙基0.1724苯基鼠3.383CH,CN甲苯2.4380,1463CH,CH3庚烧3.1930.2065C,H0.1607CH,CHOH间甲酚3.1800.16t?乙苯2.898C,H,CeHs0.1963C,H,oCaHs苯乙醚3.5631970CH,N(CH)2二甲基苯胺3.1990.2296CHua二异丁烷3.5430.2368C,Hie正辛烷3.781间二甲苯3.0760.1772CgttCHg)?C,HaCHs!邻二甲茶3.0380.17553,1340.1809CH,(CH,)!对.甲苯CeH,C,tf7异丙华琴3.6110.2'3"..CaHisC-H.丙基革3.6330.202y(CH)Ces3.47:t.19791.3.5-三甲基本CHs恭1.0270.1937C.aH2z奖烷0.29051.914CHu甲基异丙基苯4.2720.2336CHu1.2.4.5-四甲基苯4.5920.2424异丁基苯ani1dC.H,C,H3.910联举(CHs)25.34924.801(CH5)2CH2二苯甲烷3.8710.2246Gerl,四氯化储2.2900.1485He氧0.0034570.02370HBr澳化氢0.15090.04431HCI氨化氨11.3716n.04081Hi2氢0.021760.02661-H2S晾化氨0.44900.04287HSe硕化氢0.53380.01637H,O水0.55360.03049Hx-隶0.82000.01698Kr效0.23490.03978Ne烟0.017090.02135N2鼠0.14080.03913NHs氮0.12250.037077-
续表名化学式称a/(N.m4.mol-2)1u3b/(m3.mol-1)NO一化鼠0.13580.02789NO?二镇化気D.53540.01124A20一氮化一鼠0.38320.0441502氧0.13780.03183P磷5.3610.1566PH3磷化氢0.46920.05156PH,CI氟化0.11080.04315SiF.四城化硅0.42510.05571SiH.硅烷0.43770.057865Or二复化硫0.68030.05636Xe效0.12500.05105搞自Robert C、Weast,"CRC HandbookofChemistryand Physics66thedition（1985~1986),D-1881-3物质的临界常数表1-7有机化合物的临界温度和临界压力化学式名1./℃pe/MPaCHCIF2一氟二氯甲块964,91CHCI,F二氧一氯甲烷178.55.17CHCI,三氯甲烷2635.47CHF,三夏甲烧25.94.75CH,C12二氟烧2376.1CH,NO硝基甲烷314.86.31CH.Br一澳甲烧1948.451CHCI一氧甲烷143.86.68CHsF一氯甲烷44.65.9CH,I一碘甲烷254.87.36CH,甲烷-82.14.64CH,O甲醇2107.95CH,S甲硫醇196.87.23CH,N甲胺156.94.07CBrFs一澳兰氯甲烷675.10CCIF,一氨三瓶甲烷28.853.87CC1,F2二氯二氯甲烷111.504.018
续表名化学式称telcp./MPaCCl,F三氯一氯甲烷1984.384.6ccl,283.1四狐化碳4.19四氟甲烷-45.7CF:35.56.24乙快C?Hz30.1C?H2F?1.1-二氟乙烯乙腩274.74.83C,H,N1.1,1，兰氟乙烷73.1C..H,Fs乙烯9.05.12C2H4乙醛187.85.54C.H0195.87.2C,H,O环氧乙烷C2H,O.醋酸321.65.79甲酸甲脂2145.99C2H,O?249.85.071.1-二氟乙烷C-H,Cl?-386.7CaH.F21.1-二氯乙烷CaHsBr漠乙烷230.86.23C2HsCI氧乙烷187.25.3C2HsF氟乙烷102.165.03C2Hs烧Z32.24.88CeitO二甲醚1275.33乙醇C,HeO2436.4CaH,s5.52二甲硫醛229.9C2HS乙硫醇225.55.49C2HN二甲基胺164.65.31C,H,N乙基胺183.25.62C2Br2F4二澳四氟乙烷214.580C2CIFs一氯五氯乙烷145.7CeChzF,1,2-二氯四氟乙烷C2ClsFs214.2三氯三氟乙烷3.41C,CI,F22783.33四氟二氟乙烷C2F六氟乙烷24.3-C,H,丙二烯1204.42CsH.快丙127.85.35C,HsN丙腩290.81.18C,H,oC环氧氟丙烷323C,HsCi氯丙烯240.34.71CsHe烯丙91.94.60CsHs环丙烷124.7CiH.O酮丙235.54.8CH.O丙烯醇2725.629
续表名化学式称t./rpe/ MPaC,H.o环氧丙烷2094.92C,H.O.甲酸乙酯235.34,69C,H.O?乙酸甲酯233.74.69CHO2丙酸337.65.37C,H,C:银代丙烷2304.58C,H,丙烷95.84.3C.HaO甲基乙基164,74.40CaH.o昇异丙醇2354.8C.H,O正丙醇263.65.2C,HaN异丙胺209.7CsHeN正丙胺223.84.74C.H,O峡哺5.32213.8C,HS噻盼3075.69C,He1.2-丁二烯1714.50C.He1,3-二烯1524.32C.Hs正丁娜1464.02C.Hs顺式2-丁烯1604.10C.H反式2-丁烯1554.201CHO1.2-氧化丁烯243wC,HgO甲基乙基2624.15C,H.Oz丁酸3555.3C,HaO2对-二氯杂环己烷314,85.21C,H.O2酯酸乙酯250.43.83C,HiO2丙酸甲酯257.43.98C,H,Oz甲酸丙酯264.94.06C.o1氯代正丁烷269CAHo宁烷1523.80C,Ho昇丁烷1353.6CaHeo正丁幕289.84.42C,HiO仲丁醇2634.19C,H.0叔丁醇2353.97C.t.o乙醛192.63.61C,H,o异丁醇2774.28C,Hi,O二坨乙二醇407C.lires二乙基硫髓283.83.96C.H.N丁藏287.9C,Hi.N二乙胺223.33.71C.H.IY拜1胺266.7C,F:0全氯丁烷113.22.33.10
续表名称telrPe/ MPa化学式340.8C,lisN吡啶232.944.78C:Hs环戊烯4.51CsHio环戊烷238.61914.04C,Hio[-戊烯CsHi,O3.74二乙蘭287.8C,H0272.93.3丙酸乙酶3.48C:Hi.Oz正丁酸甲酯281.3C,Hio02醋酸正丙萄2763.33C,HieO2正戊酸3783.81C,H,N320.84.47六氢吡啶C,Hiz187.83.332-甲基丁烷C:Hi2新戊烷160.63.20CsHiz正戊烷196.63.37C;H20异戊醇309.77CgH,Br苯，澳3974.52CaHsCI氟恭359.24.52CaH,F苯氯 4.52286,95苯CeHs288.94.92CsHaO苯酚421.16.13CsHiN胺苯5.30425.6CHNα一皮考琳348CeHNB-皮考淋371.7CHN-皮考啦372.5CaHio环已愉287.3C,Hio1.3~己二烯3.30234.4CeHi2环己烷4.1280.4CeHiz甲基环戊烷259.53.79CeHi21-己烯2313.15CHi202甲酸正戊酯302.63.45C.Hi2a乙酸正丁商305.93.11C,H202正丁酸乙酯2933.06CaHi2.3-二甲基丁烷226.83.13CeHri正己烷234.23.02CeHi,0二异丙醚226.92.88C.H.O正己醇313.5CHO.三坨乙二醇(437)CeHN二丙胺2773.1C.HisYd胺318.8CeHiSN三乙胺258.93.0.11