表2气体的等容压力系数apltapapmaTPo：气体0℃时的压力10 8ap**/K-1106ap**/ K-1气体p*/kPa汽公p,kPaN236723672101.325空101,325132.5223674133.3223675HaCl2101.3253807101.3253661NH.133.3223661101.3253768SO2.101.3253663101.3253B40N203719181.6813662101.325CO413668367368.927101.3253672CO.10t.325to1.325371036753726133.322133.322KrHC1133.3223690501.3253721Xe133.322CN23720101.3253830101.325H.CH.3663101.3253678145.987C2H,366237221U1.325101.3250.3674133.3223676!1*表中P的数据为开始的压力办车数据适用的温度范谢为0～100摘自《化学便宽》改町3版、基避编Ⅱ，日本化学会编，I24。表1-3液体单质的等温压缩系数βl(av)8-apl110p.Pa-物质tr1018/pa-所trc一BiFb3.533:2714.25-HKbrd3919.13213.2s('s34.6-1152967.3SnGra2323.3302.11T14.1In302563.2-KZn3.110.2120641huva310981摘门化学使境改前3版，基磁编日日本化学会编、11-27-1211
表1-4液体无机化合物的等温压缩系数β*为液体在101325Pa时等温压缩系数。在任意压力时的等温压缔系数由公CtaV式B：计算出、式中.iarB+pB的单位是Pa，C为无因次量。PBIu"p*1108*t化学式化学式CCPa-pa-iC10-B/PaC10-8B/PaAsCl,30H2066.91017.8cCl.088.52045.820103.4250.13682.99645.7250.09246106.70.86703044.630111.8350.13683.05514.835119.50.092460.800:450.13683.08114.4450.092460.7377125.4550.13683.07844.4550,092460.6785136.365.0.13683.05244.8650.09246148.70.622750.13683.00515.5CS22091.9850.13682.93916.53099.610048.0SO2-200.09697Gecl.0.98530129.300.09637PCl,0.79030104.4200.09637sicl,S10.65230167.7NH,-20SC!.0.110,301,355105.2TiCl.00.110,1.0503085.4250.110,.0.724400.1100.575H,o050.1自《化学便竟》改订3版，基碰编Ⅱ、且本化学会编，-28。.3:
囊-5液体有机化合物的等温压缩系数B在任意压力P时的等温压缔系数由公Cllavi式8=计算出，式中B+力laplrB的单位是Pa，C为无因次量。8-0名称化学式10-° BcPaCCI.10.66251.038四复化碳CHCIs251.03810.66兰氯甲烷甲醇CH,OH257.640.9589CH,OHCH,OH乙二醇2525.440.94521523.630.9452CH,CICH,CI2512.471,2-二氯乙烷0.970CHCt2CH1,1-二氯乙烷0.9978.9125CHCICCI2三复乙磷261.05312.29CCI,CC12四减乙滑0.96212,7225丙副CH,COCH251.0238.26CsHs菲259.700.9377358.990.93778.29450.9377C,Hu25正己烤0.94335.868100.94335.154CeH,NH苯胶250,937720.066450.937717.983CoH,Cl狐苯250.937712.49450.937710.98C.HsNO,25确基军0.937718.65450.937716.79C.H,Br澳苯250,937714.044512.470.9377C,Hw25廣烧0.94336.618400.94335.907辅自《化学觉》改打3版，基碰编Ⅱ，日本化学会编、Ⅱ-28。4-
I-2气体的范德华（van derWaals）常数裹1-6气体的范镰华常数实际气体的范德华状态方程为p+n2a(V-nb)=RTV2式中4、b称范德华常数。化学式名称a/(N.m* - mol-2)1036/(m3-mol-1)Ar复0.13630.03219CHCI氧仿1.5370.1022CH,OH甲醇0.96500.06702CH,CI氯甲烷0.75700.06483CH,F氯甲烷0.46920.05264CH,NH2甲胺0.72240.05992CH.甲烧0.22830.04278co一氨化碳0.15050.03985cOs氧硫化碳0.39850.05817CO2二氨化碳0.36400.04267CS1二硫化1.1770.07685Clz氧0.65790.05622CCI.四氧化2.0660.1383CzH2乙炔0.44480.05136CH,CN乙清1.7810.1168C.H,乙婚0. 45300.05714CH.COOH蓄敏1.7820.1068(CH2Br)21.2-二澳乙烷1.4170.08664(CH,CI )21,2-二氯乙烷1.7130.1086CH.CHCI21.1-二氯乙烷1.5710.1073HCO,CH甲酸甲1.0980.08086C,H,CI氧乙统1.t050.08651C,HOH乙醇1.2180.08407C,Hs乙烧0.55620.06380C.H,SH乙硫醇1.1390.08098(CH$)20甲醛0.81800.07246(CHs),S甲硫酸1.3040.09213(CH)2NH二甲基胺1.0520.08570C,HsNH2乙胺1.0740.08409C,N,氟0.77690.06901CHCN丙腈1.6660.1064CsHe丙烯0.84900.08272(CH)CO再顺1.4090.0994.5
续表10tb/(m3+mol -t)a/(N.ml.mol-2)名栋化学式0.1187丙酸2.038CH.COOH1.6120.1141C,H,C1氟丙烷CHs丙烷0.87790.084451.5120.1019CstiOH丙醇丙胺1.5190.1090C,H,NH2三年基胺1.3190.1084(CH,)sNC,H,S噻吩2.0990.1270(CHsCO)2乙酸酐2.0160.1263C,H,CN丁腊0.15962.606C,H,OH异丁醇1.7260.1143C2H,COOCHs2.0170.1360丙酸甲酶HCO,C,H,甲酸丙酯1.9200.1280CH,CO,C,H5乙铃乙借2.0720.1412CHio正丁烷1.4660.1226C,Ho异丁姨1.3040.1142(CzHs)20乙醚1.7610.1344(C,Hs)S乙流溅1.9000.1214(CH)2NH二乙基胺1.9400.1392(C,H)NH二丙基胺2.8090.1820:CsHio正戊娜1.6110.1207..CsHIo鼻皮烯1.8320.1405HCO,C.H甲酸异丁酯2.284n.1476C2H,CO,C,Hs2.471丙蒙乙酯0.1615CH,CO+CH异丁酸甲酯2.4820.1637C,H,CO,CH,丁胶甲酶2.4260.1569CsHu正戊境1.9260.1460tessHa异皮院1.8290.1417o.Hs萃1.8240.1154C,H,Br澳華2.8940.1539C.H,CI氧苯2.5770.1453CeHsI磷米3.3520.1656CeH.F抓革2.0190.1286*CeHsNH使2.6850.1369C.HuCN脯.己3.4610.1984CeH已境2.4710.1735CH,CO,C,Hg乙酸异丁酯2.8880.1833HCO,CsH1甲酸皮2.7950.1730C,H,CO,CH皮酸甲酯2.9340.1845C,H,CO,C,Hs丁蒙乙酯3.0470.1919.6