Table1925Table1924Table19 (cont.)0.50-60-70-80-91-0121-41-61-82-02-53-00-20-30-0010-0020-0050-010-020-050-0-4MolalitySalt0-6050-5850-5890-554/0-5410-5280-5070-4890-4730-4610-4500-426b0-9670-9560-9340-9110.88008260-7580-6960-6570-628NaBrO30-7150-7120-7100-7100-7110-7120-7100-7230-7300-7370-7440-7790-8140-7870-7500-7310-720fNaCNS0-6810-6730-6670-6620-6590-6570-6540-6550-6570-6620-6680-6880-71460-9650-0520-9280.9030-87200-8220-7780-7360-7100-693Nacl0-5890-57005630-5530-5460-5380-8260-5150-645,0-630 0-6170-6060-597D0-9650-9530-9280-9040-8730-8220-7780-7200-6880-664NaclOy0-6290-6680-6560-6480-6410-6350-6220-6160-6130-6110-6090-6090-611f0-7700-7290-7010-683NaC1040-2610-3070-2920-2800-2690-2530-2410-2330-2270-2240-2220-2250-236A0-4640-3940-3530-327Na2Cr0420-5730-6320-6160-6030-920-582f0-7650-7100-6760-651NaF0-5630-5390-5170-4990-4830-4680-4420-4200-4010-3850-3710-3430-32010-7440-6750-6200-593NaH2PO0-7230-7230-7240-7310-7360-7470-7630-7800-7900-8200-8830-9630-72f0-7870-7810-7350-727NalaNalO,0-9240-8950-8560-7840-7140-6170-5990-5830-570:0-5580-5480-5300-5140-5010-4890-4780-4550-437b0-9660-9530-0200-9050-8730-8210-7620-7030-6660-638NaNO30-6000-6800-6810-6790-6780-6780-6810-6860-6920.7000-7000-7430-7840-9000-8710-8180-7600·7270-7080-6971NaoH0-2660-2480-2330-2270-2100-2010-1860-1750-1650-1580-1820-1420-137-0-8870-7140-6420-5360-440-3650-3200-2890-8470-778Na2S040-2920-276 0-2620-250-24220-2340-2220-2140-2070-2020-1980-1950-199f0-4570-3820-3400-313Na28203a0-7900-7280-6370-5600-4870-398NdBrs0-264 0-2720-2840-3010-3210-3440-4030-4800-5770-7040·8670-4810-3930-3100-2720-2610-2590-7890-7270-6340-557Ndcl0-4640-4710-4820-4960-5100-5360-5800-6470-72008000-9001-2301-6920-5220-4700-4650-460NiCl20-0630-0560-0520-0470-0440-0420-0390-0360-0350-0340-0340-035e0-1500-1000-0840-071NiSOAa0·7940-6870-581PbBr20-8590·8030-7040-6120-497PbCl20-7900-7200-6370-5600-4880-399PrBr30-2620-2680-2810-2970-3100-3380-3950-4670-5580.6750-8250-7880-7260-6320-5530-4770-3870-3110-2730-2600-258Prcls0-6320-6170-6050-5950-5860-5780-5650-8560-5470-5410-5360-5260-520f0-7630-7060-6730-60RbBr0-6340-6200-6080-5990-5900-5830-5720-5630-5560-5510-5460-5390-536b0-8160-7640-7090-6750-652Rbcl0-9270-9030-8700-6290-610-6020-5910-5830-5750-5620-5510-540-5370-5330-5240-518r0-7620-7050-6710-647Rbl0-5340-5080-4850-4650-4400-4300-4020-3770-3560-3380-3210-2850-257国0-7340-6580-6000-565RbNOs0-2790-2630-2490-2380-2280-2190·2060-1960-1890-182N0-4510-3740-3310-301Rb28040-2980-3160-339 0-3690-4050-4430·5440-6770-8531-089e0-3200-2880-2820-287Secls0-2710-2800-2960-3140-3360-3620-4240-5090-6160-75609400-7870-7250-6310-5510·4740-2670-266Smcl,0-3840-3140-27830-8090-7160-6240-5120-3980-2830-233SnC120-4670-4730-4840-4970-5150-5350-5830-6430-71508000-90610-4680-4650-5260-483SrBr20-4300-4310-43+0-4410-4490-4610-4800-52:0-5650-6140-6700-8501-12660-900-5110-4620-4420-4330-870-810-760-700-62Srclz0-5360-5550-5780-6050-6420-6800-7730-8851-0211-1911-407t0-8530-5200-5170-524Srl20-329 0-3140-3020.2920-2830-2750-2620-2530-2440-2380-2320-2230-217f0-348Sr(NO3)20-4780-4100-3730-876TICLa0-9620-9460-527f0-7300-6520-5990-559TICIO410-7020-6000-5450-500TINO,0-1890-1880-1910-1950-2010-2070-2240-2460-2690-2960-3260-4000-486e0-2700-220-2030-192Th(NOg)40-5170-5320-5490-5710-5950-6200-6780-7440-8160-8940-9781-2281-551f0-5440-5100-5200-505UO2Cl20-7900-8710-9691-2261-3901-8042-384-2913-3730-91-083-175-91s0-6260-6340·6690-723UO2(CIO4)20-5420-5630-5870-6516807730-8680-9751-2371-6262-031-0990-5510-5200.5180-526UO2(NO)206-0391-0367-0566-05180139-0409037908720370-0383a0807-0689UO28040-1500-1020-278/0-2910-5660-7011-1360.300-350-4620-3140-2780-2690-271YCls0·7880-7200-6310-5510-4760-3850-5110-5190-5810-5980-57260-6800-6000-5470-5100-5020-504ZnBr20-3940-2850-2870-280+0-770-710-640-560-5150-4620-4320-411ZnCl280-880-840-6290-6700-929-38745-159-99f0-5810-5640-5730-596Zn(C1O4)20-6100-6401-0071-0281-0701-1230-8000-8700-9280-972g0-7460-6900-5640-582Znl20-8510-7990-6210-5810-5590-4730-4800-4890-5010-5180-5350-5740-6250-6800-7740-8171-0491-363f0-5310.4890-4740.469Zn(NOs)20-0630-0570-0520-035040480-0380-0360-0850-0370-0410-7000-6080-4770-3870-2980-202:0-150/0-1040-0830-071ZnSO4a- J For methods used, see footnote on page 20
26Table20Table202720STOICHIOMETRIC MEANMOLAL ACTIVITYCOEFFICIENTS FOR AQUEOUS SOLUTIONS ORSALTS OF ORGANICACIDSAT26°CMolality010-20-30-400-60-70-80-9-51-61-82.02.53-05-0-0SaltCaOOCCH,0-7990-7710-7610-7890-7620-7680-7760-7830-7920-8020-8260-8530-8830-9160-9501-0411-1451-263KOOCH,0.7960-7600-7840-7800-7510-7540-7500-7660-7740-8540-8810-0100-0951-0861-1810-7830-8030-827KTola0-7620.7020-6620-6320.6050-5820-5600·5410-5230-4240-4010-3800-3470-3170-2020-5060-4760-448KOOCCH2COOH0-7590-7020-6650-6340-6100.5880-5700/0-544/0-5410-4600-4500-4270-4080-3920-3770-3650-3530-5280-5070-4880-4800-472K00C(CH2)2CO0H0-7620-7080-6680-6400-6190-6020-588/0-5750-5640-4930-4780-4680-4630-4570-4530-55310-360-5910-5160.5100-501KO0C(CH2)4COOH0·772-6600-6540.6420-6310-6220-6150·609LiOOCCH:0.7840-7420-790-7090-7000-6910-6860-6890-693/0-7000-7090-7620-7980-8370-87710-7190-729LiTola0.7720-7230-6950-6740-6590-6470.6380-6300-6230-5580-5560-5590-5660-8750-617,0-6060-5950-5860-5750-568NaOOcH0-7780·6960-6850-6760-6670-6640-6610.6560-6560-6570-6880-6670-6780-691NaOOOcH0-7910-7570.7430-73707350-7360-7520-8090-8510-9140-9821-0570-75710-7690-781829NaO0CCH2CH:0-8000-77207630-7620-7640-7690-77710.7971-16008080-833Na00C(CH2)CH0-8000-7740.7610-7740-7820-7950-8190-83010-8481-2781-3680·8680861-182NaOOC(CH2):CH0-8000-7760-770-7800-7900-805N0-8521-0270-9820-9011-0300-8680-907NaOOC(CH2)CH0-8030-7790.7750-7830-7940-8100-8260-8410-8510-6730-6120-5760-5560-5420-858NaOOC(CH2)sCH)0-8030-7800-7770-7800-7830-7810-7700-7540-7000-6500-3080-3400-3060-2840-2670-2550-248NaOOC(CH2CH)0-6930-6210-500-2790-2530-2360-2060-1860.4010-3480.300NaOOC(CH2)CH)0-3900-330-2050-2640-23900-1260-1521300.219NaOOC(CHa)sCH)0-2850-244|0-2120-184/0-1691070-0970-089NaTola0-7650-7090-6740-6480-6270-6090-593-5790-5660-4930-4270-4020-3830-3680-5540-5320-5110-4760-460LNaOOCCHa(eis)0-4300-3540-3140-2800-2720-2620-2500-243/0-2360-2100-2200-2160-2140-2130-2310-224NaOOCCH2(trans)0-4650-4020-3690-3480-3350-3280-3230-3200-319000-3300-3360-343-319NaOOCCHCOOH0-7640-700-6740-6470-6260-6090-5950-58205720-5230-5140-5070-4900-4770-4670-4580-4510-4450-5630-5460-5330-528Na00C(CH2)C00H0-7660-7120-6770-6530-6350-6180-6070-30-5860-5290-5260-5240-5250-5280-534..S0-538Na00C(CH)24C00H0-7760-7300.7030-6830-6700-6580-650RbOOCCH0-7960-7670-7660-7530-7550-7890-7660-7730-7820-8690-9000-9331-0231-1261-2400-7920-8150-840TIOOCCH;0-7500-6860-6440-6140-5890-6700-5530-5390-5260-4220-4050-3890-3760-3640-3540-51|0-496| 04800-4660-4040-444s Tol Toluene sulphonate
29Table2128Table21Table21 (cont.)21MOLALSTOICHIOMETRICMEANACTIVITYCOEFFICIENTSAQUEOUSFORCONCENTRATEDINORGANICELECTROLYTESAT25°C8-09-010-03.54+55-06-07-0Molality4-0SaltMolality3-54-55-06-07-09-04.08-010-0Srl21-4921-9770-2140-212SaltSr(NOsh0-5680-6470-7220-791AgNO30-2290-2100-1940-1810-1590-1420-1290-1180-109Th(NOs)47503·8970-4160-2358CaBr26-2810-6618-4755-8163375696UO2(C1O4)22·412-682·893-06Caclz2:082-034·1726-034-2UO2(NO,25-8911-1118-2843-0-0500-0571-0401-0433-046Ca(NO,h20-4050-4350-4690-5070·5920-6900-801UOS040-7741-1491-4391-8092·260-930ZnBr20·6260-6640.714CdBr2-0290-02780-3540-4170-4990-6070-7370·8980-2950-3070-328Cacl2-0325-0263Zncl2-0306-0291-02792-803-574·47Znl21-1881-2591-3571-4761-7742-20CaSO.0-0362·993-886-415-101-7732-31CoBr27-6211-0215-36(atm=5-5,y=20-6)Zn(NOsh2-221-832Coclz62Colz13-62440102130150174214Co(NO)21-5261-9722-553-31(utm=5-5,y=4-23)0-4550-453CeBr0-4600-457CeCl0-4750-4740-4740-4750-480CuCl20-5470-5730-5970-6210·6732·052·084-215·79Cu(NO,)21-1181-3811-6901516121314Molality11HCI1-5181·7622-042-383-224-375·907-9410-44HCIO1-7262-082-533-114.767-4411-8319-1130-9Balt0-208H8040-1550-1700-1880-2570-3170-3860-4670·8590-1020-0960-090AgNO3KBr0-6000-6080-6160-62627-334-142-4HCI21-813-5117-25KENS0·5330-5290-5260-524500-0205-0322-0HCIO450-1129-580-8KCI0-5720-5770-5831-2340-9671-0930·7420-830H28040-643KT0-6620-6730-683KOH8-1013-215-819-624-610-51-72KOH1-2151-3521-532-209-883-774-866-22146-0198-0LiBr31-046-370-6104-72-28LiBr1-5841-8972-743·926-768-6112-9219-9237-926-231-9Licl12-5516-4120-9Lici1-3171-5101-7412-022·725:103-716-969·402-692-953-20LiNO,LiCIO41-8662-180-1800-1740-2100-2020-1940-186NHNO,LiNO,1-0441-1251-2161-3101-5061-7322.441-9522-1911-588-019-745-196-500-481NaOH4-10LiOH0-4874-635-903-39ZnBr2MgBr27-1512-221-136-6(atm=5.63.y=71-2)2-181-2041-73Zncl2MgCl23-565-548-7413-95(atm=5-84,y=31-6)6-52Znl217-6534-1Mg(CiO4/2(atm=44,7=86-6)18-029-057-6115Mg121-0841-2351-3951-551-882-25MnCl22-68Mns040-0420-018NH.CI0-5600-5600-5610-5620-5640·566(m=7·390,y=5.66)NHANO0-3480-3310-3160-3020-2790-2610-2210-2450-2320-8650-929NaBrNaCNS0-8540-897222517181920MolalityNacl0-7460-7830·8260-8740-986NaCIOA0-6170-6260-6370-6490-677SaltNaH,PO.0-3050-2930-2830-2760·265H,S041-3870-396NaNO:0-4220-4080-3860-371485-0260-0331.0411-0LiBrNaOH0-8350-9030-9851-0771·6032-012·553-231·29962-4Lic43-849-956-3Na2S040-1350-1350-1450-1350-153NEANO0-1680-1630-158Niclz2-263.764·692-96(atm=5-8,y=6-43)28-023-115-4117-3819-33NaOH13-47RbBr0-5160-5140-5140-5156-927.86ZnBr2Rbcl0-5360-5380-5410-5463-462-633-06ZnolRbi0-5150-5160-5160-517RbNO0-2340-2160-200
30Tables 22and 2331Tables24and2522 THE IONIC ACTIVITY FUNCTION OF WATERVALUESOFTHECONSTANTS&,BAND D:24YYOm/AH2OIN SALTSOLUTIONSIntheequationlog1oy±(25*C)-e(n Vel(1+A'Ve)+Be+De2,Valldupto4mConstants for the equationlogi00omm0)=-2euv1+4++b01+(o+01For valuesore(n and A'seeTable1sForvaluesofe(nandA'seeTable13,Validup toSmandfrom0°to50°C forNaCland KCloPto40°CforKBr,LiBrandNaBrandfrom10°Cto40°CforLiC.1lonlestrength,E= temperature in "C,yStolchiometrie molal activity coefficientSaltaBDSaltaBDCsBr2-50-01620-0033KC3-850-01870-0034Saltdb,×104C×104boCoCeCl2-50-0229KI3-950-04400-00160-0024Cel2-5KOH370-01400-00-1294KBr4-20.20512-75-0-016-9.0HBrNaBr4·20-00644:40-1650-0590KCI3-6HCI4-20-00530-2665-200-03504·884·30-1292Nacl0-04100-00615HINal4-20-0058LiBr4.215-50-17250-01280-0900-0000-00+0-0475-2·20LiBr3-244-30-1260-0099NaoH0-0460Lici3.62-000-039-4.0+0.0326Lici3-20-01934-250-111RbBr0-00210-0070NaBr4·20-1576-75+0-010-6·57LilRbci3.20-00235-00-1550-01130-0235Nacl3.60-1982-000-00852.03·2KBr3-850-02470-0035RbI0-01620-0031aValid upto Im only.23 VALUES OFTHE CONSTANTSnAND&y+=Stoichfometricmean molal activitycoeflicientin the equatlon (valid tommax.).molar concentration (moles solute per litre solution)logloy±(25°0)=-e(nVe/(1+4e)-(n/v)logioau-logid[1-0-018(n-p)m)Forvalues of Suny and A'see Table13.SaltaSalta4nmmnr.mmax'25STOICHIOMETRICMEANMOLALACTIVITYCOEFFICIENTSAT 25C FOR SOLUTIONSOF HYDROCHLORIC ACIDIN NON.BaBr24-6810-71-5LiCIO45·638-71-0AQUEOUSSOLVENTSANDAQUEOUS-NON-AQUEOUSMIXTURESBaCl27.74-451-8Lil5-609-01-0Bal2Thecompoestiomofmixtures Inexpresed anweighitpercentofnon-aqueous oomponentand5-4415-01-0MgBr25-4617-01-0the reference state is infinite dilution in the given solvent mediumCaBr213·75-0214·61-0MgCl25-021-4Cacl,12-04·731-4Mg126-1819-00-7Cal20-75·6917-0MnCl24-7411:01-4GlucoseAcetic acidCoBrz115-3516-NHCI3-751.66-010%15%20%25%30%100%m5%40%50%CoClz4-8113-01-0NaBr4-244-24-0Col220-0-95-93Nacl3·973·55-00-0010-3570-0004Fecl24-802-112·01-4NaC1O44-044-00-0020-00160-184HBr5-188·61-0Nal4-475-51.50-0050-9290-9420-9230-9440-9180-9410-9120-00360-1430·906HCI4-478-01-0Nicl24·8613-01-40-0070-00640-1110-01HCI045-092-00-9040-9070·8890-9030-8690-010.0917·4RbBr3·480-91-50-8870-8970-8770-020-8770-8730-8550-8670-8490-8560-8410-8300-02250·064HI5-690-710-6Rbcl3·491-21-50-030-8310-8280-8170-8070-040-048KBr3-852-14-0Rbl3·560-61-50-050-8330-8290-8050-8180-8000-8110-7850-7760-06250-040KCL3-631.94-012-7SrBr24·891-40·070-8160-8110-7850-8010-7790-7930-7640-7550-090·034KI4-162·54-010-71-8SrCl24·610.10-7990-7940-7660-7330-12250-0290-7820-7600-7740-743LiBr4-567·61-51-0SrI25·5815-50·20-7690-7650-7800-7460-160-025Lici4-32711-020.00-76-18Zn(C104)20-30-7590-7530-7430-7390·60-7630-7620-7440·7430.70-7760-777y±=Stoichiomctrice mean molal activity coeficientmmolality (moles solute per 1000g solvent)molar concentrntion (moles solute per litre solution)=molality (moles soluteper1000g solvent)=numberofionsprodncedbydissoclation ofonemoleculeofsaltSyr = activity of water in the solution.nuumber ofwater molecules bound to theyions
3332Tables 26 and 27Table25HLTONLENESTSOSENOATOLIILTTONELOHIOLSwg.o型多婴装#装##619-0009-0美盟健多费816-00z626.0%DLA#限限限限公司ooosSAOSONNON0863866666%ot%00T#装美928-0828-0S12-0中具wo-090-02669-0爱温罗多型型98器eto画-oo婴造加国美国美服：羊COUN2%9100-0388-02F2-0美8设设##标社司GEL.O全多HE05902-0遵型发型美烈翠福6866666%001820:0福经员员%-16%·R%%8-OOOSOOONOONNNAOoo90-000:1W20-0153215353298-0.壁迎美强空惠接壁装理宝出惠昌业营业营业：美、点、 服业62T16-0028-8LE9-09F-0661.0299-0%00L0020-0星爱装201星堂190-0O-T282-022-020-0星迎美业美婴婴型189-0a%7-8o1:0美装#+86-0福902-0829-0269-0堂191200-006200-0Owg.0健蛋变多更型689-0宽墨壁烫营196.0E8108100000车128-0MLSF-0+109-0爱宝0000-0金型蒸20-020L-0989-020-0326359ooeaOES01-0092-0蛋OT919-0黑迎建塑型%0z%02916-066-0美国医理塑零药安908-0翠美蒸品馆112-0+08-0TFT-O%08爱蛋费2201-01OL-086-0D60-0880-00g0-0320-0%OL92f-0199-0919-0199-0O19-0型理618-0181:0蒸蒸蒸O2F00%99造#务#品886-0星麦聚店911-0童鑫警费理发912.0三901-0a801-0童34554%-18%90-#60660000060r80R-0O18-0提塞星经费控室116:ag-0%0g198-0蒸晨美壁N60S-028S-0821-0681-0ZL-00SI8造品0LL1-08OL-00%0145琴要00-二2蜜型#-0%9818S-0218-00110L8T-0婴美婴型美型多o9812.8-00#塑通连彩30#家品美摄费接理费经型E%288R-6警壁%026666666H028-0118-0婴装美迎装卖3超医塑51-0912-0爱型烫装型681-0O0229-0--%09%020#缘家室OY%OT098-0198-0夏身电美型室196wgo-0xo991-0358零美罗数养69-0600%%0t控型建#控经发安康装智专费接专屋室100-16ase90-0W8aaa5n1N3W20.0琴爱美安装%0%2%0%6161型#型理量咨装6688688%00TZ16-0爱发塑设型更复型室(uoo%O192鲜健#型星馆R3283533B38S88RRR9000-00壁理0S5aS0