Q: What Experiment is This? Excitation Name of experimenttype of excitation time

General Approach to Electrochemical Experiments Identify assumptions Ditusion- ass tran sort +Identify suitable boundary conditions Solye linear diffusion equation (Fick's 2nd law -use Laplace transtorm

Net flow of electrons from MNet flow of electrons from to solute solute to m .Ef more negative than Eredox more positive than Eredox more cathodic more anodic

Junction potentials Whenever we change electrolyte or solvent there is a cost in that we create a double layer (electrode)which has a small but often measureable potential We call this potential a junction potential

5 separate events must occur: -O must be successfully transported from bulk solution(mass transport) -O must adsorb transiently onto electrode surface (non-faradaic) CT must occur between electrode and (faradaic)

The Economic Case for Electrochemical Innovation New Horizons in Electrochemical Science and Technology. National Academy Press: Washington, D.C., 1986. copyright P.A.Mabrouk, 2001. All rights

第一章绪论 第二章物理常数测定 第三章有机化合物的初步检验 第四章溶度分组试验 第五章有机物官能团的检验 第七章有机元素定量分析 第八章有机官能团定量分析 第九章混合物的分离

对于简单混合物的分离,可根据混合物中各 组份的物理性质或化学性质的差异,选择适 当的物理分离法或化学分离法,将混合物分 离为单一化合物

有机物的官能团是指化合物分子中具有一定 结构特征,并反映该化合物某些物理特性和 化学特性的原子或原子团。 官能团定量分析就是根据这些物理特性或化 学特性进行含量测定的

7.1概述元素定量分析是对有机化合物中所含元素进 行含量测定,分析化合物的组成。 一般元素定量分析,主要测定有机化合物的 常见组成元素,如碳、氢、氮、硫、磷、卤 素等。氧的百分含量通常不直接测定,而是 在测得其它所有元素的含量后,从100%减去 这些数值得到