Supplement1960to60010ow00(a)(oa)(ae)(a)()(0)(r()(g）Fce(oe)(oa)2o*or97882-4S5319.2+O12*0teou5054067040178-9707a99775S009*TL'92'1I'tS2'T1899t't6*2R'86'L0'9t1*22*7+'t9'98209>1*9~860005508002022013055280[n(HssewouiroMET[tas.a?["ota[toajav UOIt0nRtounonyS10-200210.-600*puappe9020019*-10082-20910'0S10029-20016010*000190'02.09"-g:8ro1180:0180.099·290f90*01900[vo'0J60'0801.008→.1oeorayTON(HO)puappySTOTV"toasoeTO881-9o00-819-809°089'618'0805218-881159.08561-8-8 :0*2--9006-9=Ve0Ttounowy8O9to00-STTe225Tl2-12-T'1se?3332011YA!"tos&8*JUOA1OS0+$+"00srTITRg←&0992083+"00s28
Homogeneous Reaction Kinetics 302.660 No. .6 React i on S*OC1 + SO — > SOC1 + S*0 22 22 c I 30 2 SOC1 2 so 2 Amount of reactant 10 3A=5-90 A=2.0;B=18-19 A=1.18;B=21.3 1.15 20.6 1-2 18-20 1-2 19-21 2-8 9-2C 1.1 19.6 14 0.8 10-14 0.8-6 13 0.8 1-2 19-20 2 19 1.1 20.9 1.1 20.5 1.1 19.7 Addend HC1 RbCl (CH ) NC1 o 4 A1C1 3 Sbd 5 1-12 0.5-20 1-12 0.5-20 1-12 0.6-19 1-12 0.6-18 1.1 20.6 J(CHj.NCll T o * r [A1C1 J Amount of addend .08 1.04 0.01 .00 2-. 015 .009-. 017 . 04- . 67 .004-. 6 0.04 0.016 .003-. 05 0.015 0.65 0.63 0.051 0.214 0.497 .02-2.8 .5- 2 .2-. 6 .4-. 6 O.lll 0.06J 0.05J 0.04J O.OSll 0.079J 0.048"! 0.108/ Def ined massact i on 1 aw feF R feABfebCl] feAB[(CHJ .NCl] o 4 feAB[AlC! 3] R kB[A*SbCl ] 5 R Temperature 61 0 25 -22 0 25 -21 0 25 -21 0 25 0 23 -15 -15 -15 0 15 23 30 0 0 0 0 k h° 3 k° <2 < 1 <5 6.1 8.4 8.1 1.50 1.74 1.36 7.9 6.0 5.5 6 8 4.4 2.1 4.3 4.1 1.11 1.75 2.9 ^4 1.4 5.5 7.8 < ion n -8 -7 -8 -7 -6 -5 -6 -5 -4 -6 -5 -4 -9 -8 -8 -7 -7 -7 -6 -6 -6 -5 -6 -7 -8 S 13.6 14.7 14.7 18 10.4 A A° > A° 5 1.1 5 3 1 < ion n 6 7 6 6 2 Comment s * i terature L (V17 ) ( 20 ) ( 20 )( 22) ( 20) ( 20 )( 28) ( 20 ) ( 20 ) ( 28) ( 3 ) ( 10 ) ( 80 ) ( 3) ( 4) National Bureau of Standards - National Research Council December, 1959
Supplement19600961V(or)()aaoorow*uot2--oy0ot xowot5159-9-77↑a"↑n+at共旺2a6:38*226'93'92'21'9t't00ooo0ie0oOoossepaiaoMIOA['ts-aRJo.7unouyf9'0-1*puappe.1980:012600260.0f980*01980*01080'0feto'o011'0ftvo'o16200680'0S1.1980.01280°029.0o0Juoe*of2ee080'0'1puappT'1-0'T=VJosunowye10V08-61=8nreee“t0"os33UgA108"to"$+"t0s<eesee(anson)1"0'0s +"008309920?"Toos'ON9:7
Homogeneous Reaction Kinetics 302.660 No. .6 .7 React! on S*OC1 + SO — > (continued) 2 2 2 22 2 22 1 vent So so 2 so 2 ci 2 Amount of r eac t ant A-i.o-i.i; B=19-20 A^O.l Addend |(CH 3 ) 4NC1 [SbCl 5 Amount of addend 0 . 1041 0.018J o. iisl 0.041J 0.0921 0.079/ 0 . 0921 0.086J 0.0861 0.089J 0.0861 0.115J 0.0851 0.207/ 0.0831 0.327J o.osol 0.632/ 0.08 1 o.i-o.ej Def i ned massaction law R fcBU'SbCl ] o Temperature 0 0 0 0 0 0 0 0 0 0 0 k k° x 2.9 3.7 5.1 2.8 2.2 1.4 5 9 1.12 2.2 5.2 * n -5 -5 -6 -6 -7 -7 — 7 -6 -6 _ r~t x 10 6 E A A° > A° < ion n Comments * o> 3 0} (4) (16) National Bureau of Standards - National Research Council December, I960
1960Supplement60605()()C55Ce0noqwooonS**otu88&22'012*O12LOT06245544T-55222212211008S0OBT00xxkVV2e1952239O"1O'T624033383325550O02e12-23888品甲8T-5874551 [N(HO)][[uajaA2*0-10'0puepp.2-1*06'26°L-Hd1L=HA03esaN'(HO)8696.eso90-Tpueppyen9-2g01 -2-V,0meaest0yunowyTunonel~ai~yTna9-Im8g, 01~工I~yAiooes30BAAueAn1BUOITBN*108 + 1a0'10s + 1080g + 0 +"*8+"t08*sapueasr0"os+o-08+.s't.0 + C080'moos+C0ss's*$'s+09900toCoss'Ho"Toss0日ZT:89*ON
Homogeneous Reaction Kinetics 302.660 No. .8 .9 .10 .11 .12 React i on S*OBr + SO _ > SoBr2 + S*0 22 S*OBr2 4- SOCl2 -H> SOBr2 + S*OC1 2 ssci 2 + s s*->s*sci 2 + s8 CH SSO' 4- S*0 = —— > 33 3 CH SS*0" + SO 33 3 C H SSO " 4- S*0 — > 253 3 C H SS*0~ + SO 253 3 -H C <D O CO S0 0 2 S°2 A B A H 0 2 H 0 2 Amount of reactan t A^O.l 2 1-4 2 1-4 A-4-.B-1 A~lJ B~4 B>1 A~l 10 2B=l-5 not stated 10 3A=&-5; 10 3B=3-5 Addend KG1 KBr RbBr (CH 3 ) 4NBr /x = 0.5 phosphate buffer phosphate buffer + NaCl JUL - .03 .07 .18 .5 Amount of addend sat. sat. 0.01-0.3 0. 1-2 PH=7.9 PH=7.3 /X=0.1 PH=7.4 7.9 Defined massaction 1 aw k fefeci] fe[KBr] fe[RbBr] fe[(CH 3 ) 4NBr] kB feAB feAB L. •H 05 V- 0 1 25 25 25 0 0 -21 0 25 -50 -50 -50 -50 -18 25 98 25 7 17 27 41 25 25 25 25 k = fe° n t ~6 x io7 *? 1 1.2 ~5 6 1.6 1.0 1.0 ti <1 -6 -2 -4 -5 -5 -4 -3 20 t^ <300 ^ < 180 *, <4800 t <480 1.2 2 2.2 2.1 4.1 6.2 1.6 4.6 6.6 1.0 1.1 -5 -2 -1 -2 -2 -2 -1 -2 -2 -1 -1 g 13.2 10.3 ^ >1 0 x I0n '° 4 2 n 6 6 0) •*•< C 0 i o o * 0) V. 3 u. 0) •H ( 17 ) C 11) C 11 ) ( 22 ) * ( 16) (•) ( 7 ) ( 8 ) ( 7 ) <-, 1 National Bureau of Standards - National Research Council December, 1959
1960Supplement0961OCCCC5oaon**sionuot2354F0o3N9'82°62°6auOT39-2?333322215352222934-92T21e3488*99'66'T313:1589631739388412928738835885348888888MEIAOeseeaieanwpueppe[0"8=Hd62=Hfr'0=fe"L=Hd6'2=d(romn20853118=Hdierso9'0=ng0=1pueppyaingg02-2-g01 :00--Vg01S-2-8g01 (9-2-Ve019-2-101 19-2-V,019gO1=V0O110 tunowyeeersRonres00TugAioBUo178n.0 + 0es'no'o"OS+FS"HOHOH108 +.s'Ho0o1rn0s +.s +08+oo)↑"OS+COSHo(Ho)1e0g.s'mo.08+sees-0s+s'o'0.s0(Ho)os'no'tCOSSHo*(°HO)092003WT:59T'ZT:'ON
Homogeneous Reaction Kinetics 302.660 No. .13 .14 .15 .16 .17 React i on (CH ) CHSSO" + S*0 = —— > (CH ) CHSS*0~ + SO = 32 3 3 (CH ) CSSO " + 3*0 — > 333 3 (CH ) CSS*0~ + SO 3 3 3 3 CH : CHCH SSO " + S*0 = — > 223 3 CH :CHCH SS*0~ + SO ~ 223 3 C H CH SSO ~ + S*0 " — > 6523 3 C H CH SS*0~ + SO = 662 3 3 CH OOCCH SSO ~ + S*0 = —— > 323 3 CH OOCCH SS*0 " + SO = 323 3 c 43 > O CO H 2 0 H 20 H 20 H 80 H 80 Amount of r eac tan t not stated not stated 10 3A=3-5; 10 3B=3-5 10 3A=3-5; 10 3B=3-5 10 3A=2-20; 10 3B=2-20 10 3A=10 3B=5 Addend /JL = 0.5 fJL = 0.5 phosphate buffer phosphate buffer phosphate buffer Amount of addend PH=7.9 PH=7.9 PH=7.3 /I =0.1 PH=7.3 M=0.1 pH=8.ol /^= 0 . 1 1 PH-7.3J PH=8.4 7.2 6.2 5.8 5.3 4.1 ** * w * «d * E — x. «= 0 0 c '-^ £ « o> « Q feAB feAB feAB feAB feAB <D 1_ n CO 0) 0- E <D f~ 25 25 7 16 26 36 18 25 37 50 25 25 33 40 50 50 50 50 50 50 50 k = fe° x I0n k° 1.5 1.3 2.3 4.5 5.8 9.6 1.9 2.5 5.3 1.1 1.3 3.5 4.9 6.7 1. 1 4.4 3.8 1.6 8.4 3.6 6.8 n -3 -6 -3 -3 -3 -3 _ p -2 -2 -1 -2 -3 -3 -3 -2 -2 -2 -2 -3 -3 -4 S 8.5 9.7 9.3 A = ,4° x iQn >i° 9 3 2 n 3 5 4 (0 +•» c 0 E E O 0 * * O i. Ol <d t_ O •4-> _J ( 7 ) ( 7 ) ( 8 ) ("> ( 8 ) National Bureau of Standards - National Research Council December, I960
Supplement1960661C(at(er)(ea)(or)(r)Ctoqwa.osarwn**.09-7r22218999989T00080092x00'T8g0'0'90'g9'82222o.338627322"1291252o'1222525B好55&e&&554424nMBIO2SsseepouioosunowypueppeT-$'0=r鞋aaenS'0-1'022fs'0mrf828=1?9*61=72*21=128L=12=T23071100f9°0=r2'L=Ha10=T2=*8111o3=T2OS'eN'ONEN'IONI昌2(0y0UTearudsoudpuoppy】rr*OTOHONou9°082°0-[+] '-$0-v9-2-4g01 ts-2-Ve01ado01:-8486282Josunowye8'200RR2L1284891:0-90'0-VuorO04A1086122222221ounanoieeserutaenspaeis2s+0m)/0 1m, oao'0s +0s"Ho'Ho'os-0"H + (0"m) (0'H)10.*0'wo)*0 ++%0*m)10.(0*H)0099200Jo99&:ON
Homogeneous Reaction Kinetics 302.660 No. .18 React! on (CH SSO ") + S*0 " —— > 232 3 ~SO SCH CH SS*0 ~ + SO = 3223 3 -H C > O CO H 20 Amount of reactant 10 3A=3-5; 10 3B=3~5 Addend phosphate buffer Amount of addend pH-7.3 ^=0.1 i, CO * «J «* E ~~ 1 § c z O feAB <D i. 3 -H C Q. E H- 12 25 33 43 k = fe° x I0n feo 2.8 5.8 8.4 1.4 n -2 -2 -2 -1 S w c E E O O * t- 3 -H 0> -H _J (') Chromium Ion complex, no change In valence .19 .20 Cr < H 2°> 3 F3 +Cr* V( ) 6 + 3 -* Cr*(H 0) F + Cr(H 0) +3 233 26 Cr(H 80) 6 +3 + H 20* — > Cr(H80) 8 (H aO*) + H 80 H 2° H 2° (A+L) =0. 16; (&+-M) =0.10 A=0. 05-0.1 2.40;B=36. 1 2.40 36.1 2.40 36.1 2.40 36.1 2.2C 37.7 2.13 38.8 2.02 40.4 1.71 42.8 1.9 38-39 A=0.5-1.5J [H J=0-4 0.35 0.38 JHN0 3 [NaN0 3 JHNOg (NaN0 0 O HC104 Nad 0.01 \ /^=0.5J 0., j ^=0.5] 0.1-0.5 /Z=0.4-l ^=4.3 ^=22.2 /1=22.2 /^=22.2 yU=22.2 /Z=19.6 /X= 18.3 //= 16.7 ^=13.3 NaCl,NaNO ,Na SO,., or K Fe(CN) 3 6 CIO NO ~ Br •m 1.5-5 2.7-4.4 2.3 feF E feA feAB ^A[CIO ~J ^A[NO "] Ufor-3] 22 22 27 27 27 27 30 35 40 45 45 45 45 45 45 27 27 27 1.5 6 3.3 3.4 3.6 5.0 4.0 1.00 1.67 5.0 3.5 3.2 2.7 2.3 3.3 1.3 2.2 1.2 -6 _ ? -6 -6 -6 -6 -7 -6 -6 -6 -6 -6 -6 -6 -6 -6 -6 -6 31 * ( 18 ) ( 13 )(1B ) ( 19 ) 9 tv ( 23) National Bureau of Standards - National Research Council December, 1959