8.3 Elements of Unsaturation 8.4 Nomenclature of Alkenes 8.5 Nomenclature of Cis-Trans Isomers 8.6 Commercial Importance of Alkenes 8.7 Stability of Alkenes 8.8 Physical Properties of Alkenes 8.9 Akene Synthesis by Elimination of Alkyl Halides 8.10 Alkene Synthesis by Dehydration of Alcohols 8.11 Alkene Synthesis by High-Temperature Industrial Methods 教学要求: 掌握以下教学内容:Alkenes,unsaturated compounds,.CIP sequence rules (九)Chapter9 Reactions of Alkenes2学时 主要内容: 9.1 Reactivity of the Carbon-Carbon Double Bond 9.2 Electrophilic Addition to Alkenes 9.3 Addition of Hydrogen Halides to Alkenes 9.4 Addition of Water:Hydration of Alkenes 9.5 Hydration by Oxymercuration-Demercuration 9.6 Alkoxymercuration-Demercuration 9.7 Hydroboration of Alkenes 9.8 Addition of Halogens to Alkenes 9.9 Formation of Halohydrins 9.10 Catalytic Hydrogenation of Alkenes 9.11 Addition of Carbenes to Alkenes 9.12 Epoxidation of Alkenes 9.13 Acid-Catalyzed Opening of Epoxides 9.14 Syn Hydroxylation of Alkenes 9.15 Oxidative Cleavage of Alkenes 9.16 Polymerization of Alkenes 教学要求: 掌握以下教学内容:Electrophilic addition,Bromonium ion,anti stereochemistry,Halohydrin formation, Hydration,Oxymercuration,Hydroboration,syn addition,Carbene,Catalytic hydrogenation, Hydroxylation,Ozonolysis (十)Chapter10 Alkynes2学时
8.3 Elements of Unsaturation 8.4 Nomenclature of Alkenes 8.5 Nomenclature of Cis-Trans Isomers 8.6 Commercial Importance of Alkenes 8.7 Stability of Alkenes 8.8 Physical Properties of Alkenes 8.9 Akene Synthesis by Elimination of Alkyl Halides 8.10 Alkene Synthesis by Dehydration of Alcohols 8.11 Alkene Synthesis by High-Temperature Industrial Methods 教学要求: 掌握以下教学内容:Alkenes, unsaturated compounds, CIP sequence rules (九)Chapter 9 Reactions of Alkenes 2 学时 主要内容: 9.1 Reactivity of the Carbon-Carbon Double Bond 9.2 Electrophilic Addition to Alkenes 9.3 Addition of Hydrogen Halides to Alkenes 9.4 Addition of Water: Hydration of Alkenes 9.5 Hydration by Oxymercuration-Demercuration 9.6 Alkoxymercuration-Demercuration 9.7 Hydroboration of Alkenes 9.8 Addition of Halogens to Alkenes 9.9 Formation of Halohydrins 9.10 Catalytic Hydrogenation of Alkenes 9.11 Addition of Carbenes to Alkenes 9.12 Epoxidation of Alkenes 9.13 Acid-Catalyzed Opening of Epoxides 9.14 Syn Hydroxylation of Alkenes 9.15 Oxidative Cleavage of Alkenes 9.16 Polymerization of Alkenes 教学要求: 掌握以下教学内容:Electrophilic addition, Bromonium ion, anti stereochemistry, Halohydrin formation, Hydration, Oxymercuration, Hydroboration, syn addition, Carbene, Catalytic hydrogenation, Hydroxylation,Ozonolysis (十)Chapter 10 Alkynes 2 学时
主要内容 10.1 Introduction 10.2 Nomenclature of Alkynes 10.3 Physical Properties of Alkynes 10.4 Commercial Importance of Alkynes 10.5 Electronic Structure of Alkynes 10.6 Acidity of Alkynes;Formation of Acetylide lons 10.7 Synthesis of Alkynes from Acetylides 10.8 Synthesis of Alkynes by Elimination Reactions 10.9 Addition Reactions of Alkynes 10.10 Oxidation of Alkynes 教学要求: 掌握以下教学内容:Acidity of Alkynes,Addition Reactions of Alkynes,.Oxidation of Alkynes (什-)Chapter11 Conjugated Systems and Orbital Symmetry1学时 主要内容 11.1 Introduction 11.2 Stabilities of Dienes 11.3 Molecular Orbital Picture of a Conjugated System 11.4 Allylic Cations 11.5 1,2-and 1,4-Addition to Conjugated Dienes 11.6 Kinetic versus Thermodynamic Control in the Addition of HBr to 1,3-Butadiene 11.7 Allylic Radicals 11.8 Molecular Orbitals of the Allylic System 11.9 Electronic Configurations of the Allyl Radical,Cation,and Anion 11.10 SN2 Displacement Reactions of Allylic Halides and Tosylates 11.11 The Diels-Alder Reaction 11.12 Ultraviolet Absorption Spectroscopy 教学要求: 掌握以下教学内容:Stabilities of Dienes;:Molecular Orbitals of a Conjubated System;Allylic Cations;1.2-and 1.4-Addition to Conjugaed Dienes;The Diels-Alder Reaction. (+)Chapter 12&13 ((READING OUT OF CLASS) Chapter 12 Infrared Spectroscopy and Mass Spectrometry Chapter 13 Nuclear Magnetic Resonance Spectroscopy (十三)Review and Discussion1:Hydrocarbons and new applications1学时 (十四)Chapter14 Structure and Synthesis of Alcohols2学时
主要内容: 10.1 Introduction 10.2 Nomenclature of Alkynes 10.3 Physical Properties of Alkynes 10.4 Commercial Importance of Alkynes 10.5 Electronic Structure of Alkynes 10.6 Acidity of Alkynes; Formation of Acetylide Ions 10.7 Synthesis of Alkynes from Acetylides 10.8 Synthesis of Alkynes by Elimination Reactions 10.9 Addition Reactions of Alkynes 10.10 Oxidation of Alkynes 教学要求: 掌握以下教学内容:Acidity of Alkynes, Addition Reactions of Alkynes, Oxidation of Alkynes (十一)Chapter 11 Conjugated Systems and Orbital Symmetry 1 学时 主要内容: 11.1 Introduction 11.2 Stabilities of Dienes 11.3 Molecular Orbital Picture of a Conjugated System 11.4 Allylic Cations 11.5 1,2 -and 1,4-Addition to Conjugated Dienes 11.6 Kinetic versus Thermodynamic Control in the Addition of HBr to 1,3-Butadiene 11.7 Allylic Radicals 11.8 Molecular Orbitals of the Allylic System 11.9 Electronic Configurations of the Allyl Radical, Cation, and Anion 11.10 SN2 Displacement Reactions of Allylic Halides and Tosylates 11.11 The Diels-Alder Reaction 11.12 Ultraviolet Absorption Spectroscopy 教学要求: 掌握以下教学内容:Stabilities of Dienes; Molecular Orbitals of a Conjubated System; Allylic Cations; 1,2- and 1,4-Addition to Conjugaed Dienes; The Diels-Alder Reaction. (十二)Chapter 12&13((READING OUT OF CLASS) Chapter 12 Infrared Spectroscopy and Mass Spectrometry Chapter 13 Nuclear Magnetic Resonance Spectroscopy (十三)Review and Discussion 1: Hydrocarbons and new applications 1 学时 (十四)Chapter 14 Structure and Synthesis of Alcohols 2 学时