Maxwell关系式的应用ZHEIANGUNIVERSTYOSCIENNCATECHNGauavavCOpop十=T(alOTonaTa7OUav对理想气体DaavnRapa: dU =- Tds - pdvp令等温对V求偏微分nRasOUV-pavanRTCCnR=nRapaspV(Maxwell式ava1Cp.m=RCymouap-p对凝聚态CV~0alOT12Zhang Li-qing2019/10/12
Maxwell关系式的应用ZHEIANGUNIVERSTYOSCIENCE&TECHNOLOGYaco"acpmpm)证明：（1p（2）理想气体T=01OT2opopacaaHOOHpm-aTDTTaTopapap: dH. =Tds. +V.dpaapmasaH)T-T+Vm7T+VLaTOTopT+11000po"avavov-TMaxwell1+POT2OTaTOTOvovm+V17T1PopaTOT13Zhang Li-qing2019/10/12
Maxwell关系式的应用ZHEIANGUNIVERSTYOSCIENCE&TECHNOLOGYacaca-VpmDm证明：（1)p（2）理想气体=（OT2opopCC0avpmnRTOTOTopmpOovavna'vOTalOT=00-VaTaacpm理想气体)_=0育op14Zhang Li-qing2019/10/12
Maxwell关系式的应用ZHEIANGUNIVERSTYOSCIENCYATECHNGQaCy证明：OTOvauO1acCOvlITavavaTalal: dU =Tds-pdvasalor7Pavalalacaop0alalalOopOrOTaT15ZhangLi-qing2019/10/12
证明题7ZHFILANGUNIVERSITYOSCIENCE&TECHNOLOGY试证明物质的量恒定的单相纯物质，只有p.V.T变化过程的Das =OrdpdOL证明：S=f(p,V)asdv.:. ds-C1paOTOTasasdv..dsdp+7OTOVOpaHnCv.mp.mOTCOT--T(T:dU=Tds-pdv: dH - TdS +VdpaHauasasOTOTOTnoCH7716Zhang Li-qing2019/10/12