Homogeneous Reaction KineticsSUBJECTINDEX(continued)Title of Table(continued)380COORDINATIVE EXCHANGE(number of pages)382Coordinative exchange (liquid)Coordinative exchange;H_o replacing 8-compoundin vIIith group(1)382.860complex1;N-compoundreplacingS-compoundinVilIth(1)382.865group complex":H,O,OH or ORreplacing halogen in VIIIthgroup complex (H_o notalways shown In complex)(22)382.870nn; N-compound replacing halogen In VIIith group(6)complex382.875n;ROHRcoo",coorScompoundreplacing(2)382.876halogen in vIlith group complex:Halogenreplacinghalogen inViiith group(a)complex382.877400ELIMINATION400PROTON ELIMINATION Supplement402Protonelimination(liquid)Proton elimination; proton elimination from oH-bond (carboxylic acids(3)and phenols,ionization and recombination)402.461420BOND-UNSATURATION ELIMINATION1960422Bond-unsaturationelimination(liquid)Bond-unsaturation elimination; Hg(ll) from ethylenic addition(5)compound422.421430RING-CIOSURE ELIMINATION432Ring-closure elimination (liquid)Ring-closure elimination;elimination orhydrogenhalide from halo-(8)432.471hydrinswith ringclosure#elimination of hydrogen halide,or halide(11)lon to form N-containing ring432.475December,1960National Bureau of Standards -National Research Council
Homogeneous Reaction Kinetics SUBJECT INDEX (continued} Title of Tab Ie 380 COORDINATIVE EXCHANGE (continued) (number of pages) 382 Coordinative exchange (liquid) Coordinatlve exchange; H SO replacing s-compound in VI nth group complex (1) 382.860 " " ; N-compound replacing s-compound in Vlllth group complex (1) 382.865 " " ; H go, OH~ or OR~ replacing halogen in villth group complex (R^Q not always shown in complex) (22) 382.870 " " ; N-compound replacing halogen In Vlllth group complex (6) 382.875 " " J ROH, RCOO , CO ~ or S compound replacing halogen in Vlllth group complex (2) 382.876 M " ; Halogen replacing halogen in Vlllth group complex (1) 382.877 4oo ELIMINATION 400 PROTON ELIMINATION tl-02 Proton elimination (liquid) t§ Proton elimination; proton elimination from OH-bond (Carboxylic acids ^ and phenols, lonization and recombination) (3) 402.461 § (to ^ 420 BOND-UNSATURATION ELIMINATION ^ U22 Bond-unsaturation elimination (liquid) ^ Bond-unsaturatlon elimination; Hg(ll) from ethylenic addition S compound (5) 422.421 430 RING-CLOSURE ELIMINATION >432 Ring-closure elimination (liquid) Ring-closure elimination; elimination of hydrogen hallde from halohydrins with ring closure (Q) 432.471 " " ; elimination of hydrogen hallde, or hallde ion to form N-containing ring (11) 432.475 National Bureau of Standards - National Research Council December, i960
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1960Supplement209611eqwe000CCCCCe***Bauewono9-9-9-"85r2812Tot.o02*9]0'959999655eei uoitodaaVAV&-8swpoio100t91:0912°09'09'0puppeotunow0s''0H0-4Hos'H"0"Ho-4H"0s'H"5'Ho--puoppv"os"H"os"H010ToAoHOOD"HOHOOD"HOHOOHO2(9+p3eo0e0t 0ouetkdoon16-0--1t0oeoto01l+-0)Ciounoooaeseyeuoaenspeepueiso neeangeuoien HOO"HO ++HOO"HO +Ho0'Ho +HOO(''0) OH0*(H0)HDOOO(HO)HOHO(O) (H0)*(H'0)HoCH'0)0ottoegSHOO0,100HO('O)HTDH0"(H0)“HoOO(O)HoHo*('0)10000o100oHH7HU0-4oo"Ho200SvOOVO十EHH21HOO21'4S:9'ON9
Homogeneous Reaction Kinetics 302.440 No. .13 .14 .15 .16 .17 React ion CH OAC VT\E )<^ OAC H p) + ^s 000" ~* Ann N >^ -. OOC 14CH 3 H OOCCC1 3 (2-0-t ri chloroacet y l-OC~D-g 1 ucopy ranose tetraacetate) CH2OAc H X| ° \ OOC 14CH 0 { / P \ i < H Ni + CH COOH — > \ OAC H A 3 AcO \1 JX H H OOCCC1 3 (2-0-tri chloroacety 1-yS-D-g lucopyranose tetraacetate) (C H ) CHC 14H(C H )OOCCH — > 652 65 3 CH COO(C H )CHC 14H(C H ) 3 60 652 (C H ) CHCH(C*H )OOCCH —— > 652 66 3 (C H ) (C*H )CHCH(C H )OOCCH 6565 65 3 652 65 3 3 (C H ) CHCH(C H )OOCCH + CH C 14OOH 652 66 3 . 3 Sol vent (CHg CO) 2 0 + CH COOH 3 (CH3 CO) 20 + CH gCOOH CH 0 COOH o CHGCOOH j CH.COOH o Amount of reactant A=0.l;B=50# of solvent A=0.1;B=50% of solvent 10 A= 1.25 10A=1.25 10 A= 1.25 Addend H^^ H 2 S°4 A 4 #>-CH3C6H4 S03 H C H SO H 364 3 ^-CH3C8H4S0 3H H- O -o C c -S 1 * -1 0.5 0.5 0.126 0.126 0.126 0.276 e ~~ -o c c ~ *0 (tf feA k A * FE ftF E * FE <D •*"* i. 4) O. 0 k- 25 25 55 55 55 55 k = k° x ion 0 1.83 2.0 6.2 6.0 6.4 1.33 n -6 -5 -6 -6 -6 -5 en c 0 £ E O o * * * 9> 3 -*-1 k_ -t-" _J (°) ( / ( 8 ) ( 8) ( 8) CO 8 National Bureau of Standards - National Research Council December, I960