厦门大学化学化工学院:《有机化学》课程教学资源(课件讲稿,双语版)Chapter 8 Alkenes and Alkynes II:(8.1-8.4)Introduction:Additions to Alkenes

In the addition of HX to an unsymmetrically substituted alkene, the hydrogen atom adds to the carbon atom of the double bond that already has the greater number of hydrogen atoms and that the X group adds to the carbon having more alkyl substituents. Markovnikov’s rule can be restated by saying that, in the addition of HX to an alkene, the more stable carbocation intermediate is formed.
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