螺旋构象 全同聚丙烯 H MH MH MH MH MH MH M MPM MPMMPMPM H H H H H H 0.4nm CH3 每3个CH2CH-转一周 CH3 O=CH3.,, -CH=CH2, -OCH3 记作31或2*3
螺旋构象 全同聚丙烯 0.4nm CH3 C C C C C C C C C C C C C C H H M H M H M H M H M H M H M M M M M M M M 每3个-CH2-CH- 转一周 CH3 记作31或2*3/1 H H H H H H =CH3 , -C2H5 , -CH=CH2 , -OCH3
CH O=-CH2-CH(CH3)-C2H5, -CH(CH2)CH(CH3) 2*7/2 2*4/1 2*4/1
= -CH2-CH(CH3)-C2H5 , 2*7/2 -CH(CH2)CH(CH3)2 2*4/1 CH3 2*4/1
等规聚丙烯 (单斜晶系) b a 3A
等规聚丙烯 (单斜晶系) a b 3Å
N●M 4×3)×42 N·6023×103×665×20.96×650×1024×sin9920 =0.939(g/cm) ∧^W MV B=9920 c=6.50A
0.939( / ) 6.023 10 6.65 20.96 6.50 10 sin 99 20' (4 3) 42 3 23 24 g cm N V N M A c = = = b=9920’ a=6.65Å b = 2 0.9 6 Å c=6.50Å
42X光行射法 A B ddd O 光程差必须为波长的整倍数 Bragg equation ao=ob= sine 2d sin b=nd n为整数,一般为1
4.2 X光衍射法 2d sin q = nl q d d d q q 光程差必须为波长的整倍数 A O B AO = OB = dsinq n为整数,一般为1 Bragg equation