第一节 表面吉布斯自由能和表面张力 第二节 曲面的附加压力和蒸气压 第三节 润湿和铺展 第四节 溶液的表面吸附 第五节 不溶性表面膜 第六节 表面活性剂 第七节 气体在固体表面上的吸附 第八节 固体在溶液中的吸附

《结构化学基础》课程PPT教学课件：第四章 分子对称性和群论基础

《结构化学基础》课程PPT教学课件：第三章 双原子分子的结构和性质

《结构化学基础》课程PPT教学课件：第二章 原子的结构和性质

《结构化学基础》课程PPT教学课件：第一章 量子力学基础知识

Idea Develops the concept of chemical potential and shows how it can be used to account for the equilibrium composition of chemical reaction Equilibrium co

简单混合物 Simple mixtures偏摩尔体积 Partial molar VolumeⅤ≠V1+Ⅴ2Partial molar volume of substance a in a mixture is the change involume per mole of a added to the large volume of the mixture

相律 Phase Rules Phase diagrams are extremely useful for systems with multiple components, and serve to describe physical and chemical equilibria over range of different compositions, as well as points where substances are mutually miscible, or even when a system has to be brought to a specific set of conditions for equilbrium to exist(e.g., pressure

Measurement of Work to determine the \direction\ of a process: \direction\--spontaneous--irreversible --non-spontaneous-- reversible --equilibrium

热力学定律— Helmholtz and Gibbs energies Consider a system in thermal equilibrium with surroundings, at temp. T For change in the system with transfer of heat, the Clausius inequality is