第二炮兵工程学院：《大学化学（工程化学基础）》课程教学资源（PPT课件讲稿）第三讲 固体、溶液

3.1 Common feature of spontaneous change 3.2 The second law of thermodynamics 3.3 Carnot cycle and Carnot principle 3.4 Definition of entropy 3.5 Clausius inequality ; principle of increase of entropy 3.6 Calculate the change of entropy 3.7 Statistical view of entropy 3.9 Direction of change and conditions in equilibrium 3.10 Calculate of G 3.11 Relations of thermodynamic functions 3.12 Clapeyron equation 3.13 The third law and conventional entropy 3.8 Helmholtz function and Gibbs function

2.1 Preface to the thermodynamics 2.2 The thermodynamic first law 2.3 Quasi-static process and reversible process 2.4 Enthalpy 2.5 Heat capacity 2.6 The first law in ideal gases 2.7 Thermochemistry 2.8 The Hess’s law 2.9 Heat in some processes 2.10 The temperature dependence of the reaction enthalpy —— Kirchhoff’s law 2.11 An adiabatic reaction ——non-isothermal reaction

Adiabatic process In Fig. PⅤ: In reversible process the work A(ply done (below the line ab) is Blp: l: big than the work done (below the line ac)in adiabatic C(:'V,) reversible process

Bilingual education I'll be teaching you Physical Chemistry this semester

5.1 The conditions of chemical equilibrium and affinity of chemical reaction 5.2 The equilibrium constant of a reaction and isothermal equation 5.3 Heterogeneous chemical equilibrium 5.4 Determination of equilibrium constants 5.5 The standard Gibbs function of formation 5.8 Coupling reaction 5.7 Chemical equilibrium of simultaneous reaction 5.6 The response of reactions to the conditions

3.1 Common feature of spontaneous change 3.2 The second law of thermodynamics 3.3 Carnot cycle and Carnot principle 3.4 Definition of entropy 3.5 Clausius inequality ; principle of increase of entropy 3.6 Calculate the change of entropy 3.7 Statistical view of entropy 3.9 Direction of change and conditions in equilibrium 3.10 Calculate of G 3.11 Relations of thermodynamic functions 3.12 Clapeyron equation 3.13 The third law and conventional entropy 3.8 Helmholtz function and Gibbs function

3.7 热力学第二定律的本质和熵的统计意义 3.8 Concentrating on the system

4.1 Introduction 4.2 Expressions of concentration 4.3 Partial molar properties 4.4 Two empirical laws in dilute liquid solutions 4.5 Chemical potential of each component in gaseous mixtures 4.6 Liquid mixtures 4.11 Distribution law 4.10 Non-ideal liquid solutions 4.9 Gibbs-Duhem relations 4.8 Colligative properties in dilute liquid solutions 4.7 Chemical potential of each component in dilute liquid solutions

利用物质的气态原子对特定波长的光的吸收来进行分析的方法