Beyond this temperature,it decomposes,rather than melts.This salt is chemically stable in organic solutions,but is reported to slowly decompose by hydrolysis to LiBO2 and LiOOCCOOH Amine et al.presented the thermogravimetric curve for LiBOB in the temperature range of 20-600 C.Yu et al.reported on the stability of LiBOB in the temperature range of 240-300 C,and on LiBOB decomposition to Li2CO3,B2O3,CO2,and CO when the temperature is higher than 300 C.They observed a weight loss related to two processes at temperatures in the region of 320 Cand 450C.It was reported that the decomposition of 2 Cproduces B2O3 and CO2. PDF文件使用"pdfFactory Pro”试用版本创建www.fineprint.com.cn
Beyond this temperature, it decomposes, rather than melts .This salt is chemically stable in organic solutions, but is reported to slowly decompose by hydrolysis to LiBO2 and LiOOCCOOH. Amine et al. presented the thermogravimetric curve for LiBOB in the temperature range of 20–600 ℃. Yu et al. reported on the stability of LiBOB in the temperature range of 240–300 ℃, and on LiBOB decomposition to Li2CO3 , B2O3 , CO2 , and CO when the temperature is higher than 300 ℃. They observed a weight loss related to two processes at temperatures in the region of 320 ℃and 450 ℃. It was reported that the decomposition of LiBOB at 302 ℃produces B2O3 and CO2 . PDF 文件使用 "pdfFactory Pro" 试用版本创建 www.fineprint.com.cn
0.05 0 -LiBOB ---LiPF6 0.00 -20 -0.05 -40 0.10 -60 Heat flow(mw/mg) DTA 0.15 -80 -0.20 -100 0 50100150200250300350400 Temperature(C) The TG/DTA plots of LiBOB and LiPFa electrolyte. PDF文件使用"pdfFactory Pro”试用版本创建m,fineprint.com,cn
The TG/DTA plots of LiBOB and LiPF6 electrolyte. PDF 文件使用 "pdfFactory Pro" 试用版本创建 www.fineprint.com.cn