Distillation: Summary Distillation is a widely used separation process The separation is based on the volatility difference of the components to be separated
Distillation : Summary • Distillation is a widely used separation process. • The separation is based on the volatility difference of the components to be separated
Wide application of distillation WHY? Volatility difference exists for most mixtures Only heat is needed for the separation, no other extra agents are needed So the products may be pure
Wide application of distillation: WHY? • Volatility difference exists for most mixtures. • Only heat is needed for the separation, no other extra agents are needed. So the products may be pure
Classification of distillation Relative volatility Process Example big equilibrium H, and oil distillation or flash distillation medium fractionation Benzene and tolune small azeotropic Absolute distillation and ethano extractive distillation production
Classification of distillation Relative Volatility Process Example big Equilibrium distillation or flash distillation H2 and oil medium fractionation Benzene and tolune small Azeotropic distillation and extractive distillation Absolute ethanol production 1 2 3 4
Flash distillation dew point line bubble point line XAOT YA
Flash distillation T xAor yA dew point line bubble point line
Fractionation with rectifying section and stripping section column with rectifying section and stripping section condenser(total and partial), accumulator cooler cold water reflux and overhead product reboiler: steam and condensate bottom product
Fractionation with rectifying section and stripping section • column with rectifying section and stripping section • condenser(total and partial), accumulator, cooler: cold water • reflux and overhead product • reboiler: steam and condensate • bottom product