ETEQUATIONS-△G*/k_TB=AerateAG*=4(1+AG)2X2≥12= 2(11+222)1/2k12 = (k11 k22 k12 f12)
Ferrocene/Alkanethiol on Au51051010*101103(-s) 9y +ly10310210?10'10125℃1℃AB1001001.0-0.50.00.51.0-1.00.50.00.51.0E-E°(V)入=0.85cV.up=6.73×101sleV-!Chidsey,Science (1991)
THEINVERTEDEFFECTReactant'sCurveProduct'sCurveREACTIONCOORDINATE
10'0入s=0.75eVLower Limit入y=0.45evw=1500cm10°10S6K210K1062.00.01.0-△G°(ev)
Formationof ElectronicallyExcitedProductsEP*REACTIONCOORDINATEq