I Amides: RCONH2 Amides with an unsubstituted -NH2 group are named by replacing the -oic acid or -ic acid ending with -amide or by replacing the -carboxylic acid ending with-carboxamide
Organic Chemistry Organic Chemistry Xiamen Xiamen University University Amides: RCONH 2 Amides with an unsubstituted –NH 2 group are named by replacing the –oic acid or –ic acid ending with –amide or by replacing the –carboxylic acid ending with –carboxamide
酰胺的命名: RCONH2 g■酰胺×酸→×酰胺N-烃基×酰胺 ic acid→- amide carboxylic acid --carboxamide NH2 CH&C-NH HC-N(CH3)2 乙酰胺 环戊烷羧酰胺NN-二甲基甲酰胺 Acetamide Cyclopentanecarboxamide n n-dimethylformamide DME
Organic Chemistry Organic Chemistry Xiamen Xiamen University University 酰胺的命名 RCONH 2 酰胺 酸 酰胺 N-烃基 酰胺 -ic acid -amide -carboxylic acid -carboxamide DMF CH 3 C O NH 2 C NH 2 O HC O N(CH 3 ) 2 乙酰胺 环戊烷羧酰胺 N,N-二甲基甲酰胺 Acetamid e Cy c lop e n t a n e c a rboxamide N,N-Dime th y l fo rmamid e
Nitriles: RCN Compounds containing the-Cn functional group are known as nitriles. Simple acyclic nitriles are named by adding nitrile as a suffix to the alkane names with the nitrile carbon itself numbered Cl More complex nitriles are named as derivatives of carboxylic acid by replacing the -ic acid or-oic acid ending with nitrile, or by replacing the carboxylic acid ending with -carbonitrile
Organic Chemistry Organic Chemistry Xiamen Xiamen University University Nitriles: RCN Compounds containing the –CN functional group are known as nitriles. Simple acyclic nitriles are named by adding – nitrile as a suffix to the alkane names, with the nitrile carbon itself numbered C1. More complex nitriles are named as derivatives of carboxylic acid by replacing the –ic acid or –oic acid ending with – onitrile, or by replacing the carboxylic acid ending with –carbonitrile
腈的命名:RCN 可■腈×腈(含CN碳原子 alkanenitrile ic acid or -oic acid --onitrile carboxylic acid --carbonitrile CH CH3 0 CHrCN 一CN CN ①D 乙腈苯甲腈2,2-二甲基环己烷甲腈 a Acetonitrile Benzonitrile 2, 2-Dimethylcyclohexan carbonitrile
Organic Chemistry Organic Chemistry Xiamen Xiamen University University 腈的命名 RCN 腈 腈 ( 含CN碳原子 ) Alkanenitrile -ic acid or –oic acid -onitrile -carboxylic acid -carbonitrile CH 3CN CN CN 乙腈 苯甲腈 2,2-二甲基环己烷甲腈 CH 3 CH 3 Acet o nitrile Be n z o nitrile 2,2 - D i m ethylcyclo hexancarb o nitrile
112羧酸衍生物的结构和反应性 Structure and Reactivity of Carboxylic Acid Derivatives
Organic Chemistry Organic Chemistry Xiamen Xiamen University University 11.2 羧酸衍生物的结构和反应性 Structure and Reactivity of Carboxylic Acid Derivatives