Method Washin Drving 5471548.1 Rinse immediately with last 400C for several hours or rinse solvent used, wash with hot water with methanol and detergent, rinse with tap and 549.2 Rinse immediately with last 130C for several hours or rinse solvent used, wash with hot water with methanol and detergent, rinse with tap and reagent water 550/550.1 Rinse immediately with last 400C for 15-30 minutes or rins solvent used, wash with hot water I with acetone or pesticide quality and detergent, rinse with tap and hexane reagent water Wash with water and detergent, Vials: 400 C for 30 minutes rinse with tap and reagent water. Caps: 80C for 1 hour Rinse caps in acetone 552.1,552.2,555 Rinse immediately with last 400C for 1 hour or rinse 3 times solvent used, wash with hot water with acetone and detergent, rinse with tap and reagent water with Air d detergent for 30 minutes, rinse tap water, methanol, acetone and methyle Metals Wash with detergent, rinse with Air dry V/ nitric acid or dilute hydrochloric(-17%), rinse with reag Inorganics Wash with detergent, rinse with Air dry phosphate free detergent for ⅣV-12
Method Washing Drying IV- 12 547/548.1 Rinse immediately with last solvent used, wash with hot water and detergent, rinse with tap and reagent water 400°C for several hours or rinse with methanol 549.2 Rinse immediately with last solvent used, wash with hot water and detergent, rinse with tap and reagent water 130°C for several hours or rinse with methanol 550/550.1 Rinse immediately with last solvent used, wash with hot water and detergent, rinse with tap and reagent water 400°C for 15-30 minutes or rinse with acetone or pesticide quality hexane 551.1 Wash with water and detergent, rinse with tap and reagent water. Rinse caps in acetone Vials: 400°C for 30 minutes Caps: 80°C for 1 hour 552.1, 552.2, 555 Rinse immediately with last solvent used, wash with hot water and detergent, rinse with tap and reagent water 400°C for 1 hour or rinse 3 times with acetone 1613 Rinse with solvent, sonicate with detergent for 30 minutes, rinse sequentially with methanol, hot tap water, methanol, acetone and methylene chloride Air dry Metals Wash with detergent, rinse with tap water, soak 4 hours in 20% (V/V) nitric acid or dilute nitric(-8%)/ hydrochloric(-17%), rinse with reagent water Air dry Inorganics Wash with detergent, rinse with tap and reagent water (use phosphate free detergent for o-phosphate analysis) Air dry
Table Iv-2 Approved Methods for Primary Inorganic Chemicals, Parameters in the Lead and Copper rule. Sodium, and Turbidity [$141.23(k)(1) Methodology EPA ASTM SM2 Other Antimo ICP-MS 200.83 Hydride-AA D3697-92 AA-Platform 200.93 AA-Furnace 3113B Arsenic ICP* 200 73 3120B ICP-MS 200.83 AA-Platform 200.93 AA-Furnace D297293C3113B Hydride-AA D297293B3114B Asbestos TEM 100.25 ICP 200.73 3120B Barium ICP-MS 200 AA-Direct 3111D AA-Furnace 3113B ICP 200.73 3120B Beryllium ICP-MS 200.83 AA-Platform 200.93 AA-Furnace D3645-93B3113B Bromate 300 16 Cadmium ICP 200.73 ICP-MS 200 83 AA-Platfe 200 AA-Furnace Chlorite 07 300.16 CP will not be an ac ble procedure after 2006 ⅣV-13
*ICP will not be an acceptable procedure after 2006 IV- 13 Table IV-2 Approved Methods for Primary Inorganic Chemicals, Parameters in the Lead and Copper Rule, Sodium, and Turbidity [§141.23(k)(1)] Contaminant Methodology EPA ASTM SM Other 1 2 Antimony ICP-MS 200.83 Hydride-AA D3697-92 AA-Platform 200.93 AA-Furnace 3113B Arsenic ICP* 200.7 3120B 3 ICP-MS 200.83 AA-Platform 200.93 AA-Furnace D2972-93C 3113B Hydride-AA D2972-93B 3114B Asbestos T EM 100.14 TEM 100.25 Barium ICP 200.7 3120B 3 ICP-MS 200.83 AA-Direct 3111D AA-Furnace 3113B Beryllium ICP 200.7 3120B 3 ICP-MS 200.83 AA-Platform 200.93 AA-Furnace D3645-93B 3113B Bromate IC 300.16 Cadmium ICP 200.7 3 ICP-MS 200.83 AA-Platform 200.93 AA-Furnace 3113B Chlorite IC 300.07 IC 300.16
Methodology EPA ASTM SM2 Other Chromium ICP 200.73 20B ICP-MS 200.83 AA-Platform 200.93 AA-Furnace 3113B Cyanide Man. Distillation D203698A4500CN-C followed by Spec, Amenable D2036-98B4500CN-G Spec Manual D2036-98A4500CN-E 1-3300-858 Semi-auto 33547 lon Sel Elec. ISE) 4500CN-F Lac hat Kenda Fluoride Ion Chromatography 300.07 D432791 4110B Manual distillation 4500F-B,D SPADNS Manual ise D1179-93B4500F-C Automated Ise 380-75WE Auto Alizarin 4500FE 12971W9 Mercury Manual Cold Vapor 245.13 D3223-91 3112B Auto Cold Vapor 245.21 ICP-MS .83 Nitrate lon Chromatography 300.07 D4327-9 4110B B-10111l Auto Cd reduction 353.2 D386790A4500-NO2-F Ion Selective Elec 4500NO,-D 6011 Man Cd reduction D386790B4500-NO3E Nitrite Ion Chromatograp 300.07 D4327-97 4110B B-1011 Auto cd reduction 35327 D3867-90A4500-NOF Man Cd reduction D386790B4500-NO3E Spectrophotometric 4500-NOy-B V-14
Contaminant Methodology EPA ASTM SM Other 1 2 IV- 14 Chromium ICP 200.7 3120B 3 ICP-MS 200.83 AA-Platform 200.93 AA-Furnace 3113B Cyanide Man. Distillation followed by: D2036-98A 4500-CN-C Spec., Amenable D2036-98B 4500-CN-G Spec.Manual D2036-98A 4500-CN-E I-3300-858 Semi-auto 335.47 Ion Sel. Elec.(ISE) 4500CN-F Lachat Kenda Fluoride Ion Chromatography 300.0 D4327-91 4110B 7 Manual Distillation, SPADNS 4500F-B,D Manual ISE D1179-93B 4500F-C Automated ISE 380-75WE 9 Auto. Alizarin 4500F-E 129-71W9 Mercury Manual Cold Vapor 245.1 D3223-91 3112B 3 Auto. Cold Vapor 245.210 ICP-MS 200.83 Nitrate Ion Chromatography 300.0 D4327-97 4110B B-1011 7 11 Au 3 to Cd Reduction 353.2 D3867-90A 4500-NO -F 7 3 Ion Selective Elec. 4500-NO -D 60112 M 3 an Cd Reduction D3867-90B 4500-NO -E Nitrite Ion Chromatography 300.0 D4327-97 4110B B-1011 7 11 Au 3 to Cd Reduction 353.2 D3867-90A 4500-NO -F 7 M 3 an Cd Reduction D3867-90B 4500-NO -E Sp 2 ectrophotometric 4500-NO -B
Methodology EPA ASTM SM2 Other Selenium Hydride-AA D385998A3114B ICP-MS 200.83 AA-Platform 200.93 AA-Furnace D385993B3113B Thalli ICP-MS 200.83 AA-Platform 200.93 Lead AA-Furnace D355996D 3113B ICP-MS 200.8 3 AA-Platform 200.9 AA-Furnace D1688-90C3113B AA-Direc D1688-90A3111B 73 3120B ICP-MS 200.83 AA-Platform 200.93 Electrometric 150.110 D1293-84 4500-H-B 150.2 Conductivity Conductance D1125-91A2510B EDTA titration 3500-Ca-B2 Ium EDTA titration D511-93A 3500-Ca-D2a AA-Direct D511-93B 3111B ICP 200 3120B Alkalinity Titration D106792B2320B Elec. titration I-1030-858 365.17 unfiltered no digestion or Color. ascorbic acid D515-88A 4500-PE hydrolysis Color, phosphomolybdate I-1601-858 Auto Segmented Flow -2601-90 Auto discrete I-2598-858 Ion Chromatography 300.07 D4327-97 4110 15
Contaminant Methodology EPA ASTM SM Other 1 2 IV- 15 Selenium Hydride-AA D3859-98A 3114B ICP-MS 200.83 AA-Platform 200.93 AA-Furnace D3859-93B 3113B Thallium ICP-MS 200.83 AA-Platform 200.9 3 Lead AA-Furnace D3559-96D 3113B ICP-MS 200.83 AA-Platform 200.93 Copper AA-Furnace D1688-90C 3113B AA-Direct D1688-90A 3111B ICP 200.7 3120B 3 ICP-MS 200.83 AA-Platform 200.93 pH Electrometric 150.1 D1293-84 4500-H -B 10 + 150.210 Conductivity Conductance D1125-91A 2510B Calcium EDTA titration 3500-Ca-B2a EDTA titration D511-93A 3500-Ca-D2a AA-Direct D511-93B 3111B ICP 200.7 3120B 3 Alkalinity Titration D1067-92B 2320B Elec. titration I-1030-858 Orthophosphate unfiltered, no digestion or hydrolysis Color, automated ascorbic acid 365.1 4500-P-F 7 Color, ascorbic acid D515-88A 4500-P-E Color, phosphomolybdate I-1601-858 AutoSegmented Flow I-2601-908 Auto discrete I-2598-858 Ion Chromatography 300.0 D4327-97 4110 7
Methodology EPA ASTM SM2 Silica Color, molybdate blue I-1700-858 auto seg. I-2700-858 Color D859-88 Molybdosilicate 4500-Si-D2a Heteropoly blue 4500-Si-E2a Auto. molybdate reactive silica ICP 00.73 Temperature Thermometric 2550B odiuM ICP 73 AA-Direct 3111B Turbidity Nephelometric 180.17 2130B GLI Method Hach 0133 Annual Book of ASTM Standards, Vols. 11.01 and 11.02, American Society for Testing and Materials, 1916 Race Street, adelphia, PA 19103 2 Standard Methods for the Examination of Water and Wastewater, 18, 19 or 20th Edition, American Public Health Association 1015 Fifteenth Street NW, Washington, D.C. 20005. Except 3111B, 3111D, 3112B, 3113B, 31 14B are not approved in the 20ta Only approved in 20hedition 3 Methods for the Determination of Metals in Environmental Samples -SupplementI, " EPA-600/R-94-111, May 1994. Available at NtIS. PB 94-184942 4 Method 100.1, "Analytical Method for Determination of Asbestos Fibers in Water, "EPA-600/4-83-043, EPA, September 1983 Available at NTIS. PB 83-260471 Method 100. 2, Determination of Asbestos Structure Over 10-HmIn Length in Drinking Water, "EPA-600/R-94-134, June 1994 Available at NTIS. PB 94-201902. Methods for the Determination of Organic and Inorganic Compounds in Drinking Water-Volume 1, document number EPa 815-R-00-014, August2000 he Determination of Inorganic Substances in Environmental Samples, "EPA-600/R-93-100, August 1993 Available at ntiS. PB94-121811 s Available from Books and Open-File Reports Section, U.S. Geological Survey, Federal Center, Box 25425,Denver,CO80225- 0425. Industrial Method No. 129-71W. Fluoride in Water and Wastewater. "December 1972 and Method No 380-75WE. Fluoride in Water and Wastewater, "February 1976, Technicon Industrial Systems, Tarrytown, NY 10591 Methods 150.1, 150.2 and 245. 2 are available from USEPA, NERL, Cincinnati, OH45268. The identical methods were formerly in"Methods for Chemical Analysis of Water and Wastes, "EPA-600/4-79-020, March 1983 1 Method B-1011, Waters Test Method for Determination of Nitrite/Nitrate in Water Using Single Column Ion Chromatography, Millipore Corporation, Waters Chromatography Division, 34 Maple Street, Milford, MA 01757. Technical Bulletin 601"Standard Method of Test for Nitrate in Drinking Water, July 1994, PN 221890-001, Thermo Orion, 500 Cummins Center, Beverly, MAO1915-9846. This method is identical to Orion WewwG/5880, which is approved for nitrate analysis. ATl Orion republished the method in 1994, and renumbered it as 601, because the 1985 manual "Orion Guide to Water and Wastewater Analysis, which contained WewwG/5880, is no longer available GLI Method 2, "Turbidity, " November 2, 1992, GLI International, 9020 W Dean Rd. Milwaukee, Wisconsin 53224 V-16
Contaminant Methodology EPA ASTM SM Other 1 2 IV- 16 Silica Color, molybdate blue; I-1700-858 auto seg. flow I-2700-858 Color D859-88 Molybdosilicate 4500-Si-D2a Heteropoly blue 4500-Si-E2a Auto. molybdate reactive silica 4500-Si F2a ICP 200.7 3120B 3 Temperature Thermometric 2550B Sodium ICP 200.73 AA-Direct 3111B Turbidity Nephelometric 180.1 2130B GLI Method 2 7 13 Hach 10133 Footnotes Annual Book of ASTM Standards, Vols. 11.01 and 11.02, American Society for Testing and Materials, 1916 Race Street, 1 Philadelphia, PA 19103. Standard Methods for the Examination of Water and Wastewater, 18 , 19 or 20th Edition, American Public Health Association, 2 th th 1015 Fifteenth Street NW, Washington, D.C. 20005. Except 3111B, 3111D, 3112B, 3113B, 3114B are not approved in the 20th edition. Only approved in 20 edition 2a th "Methods for the Determination of Metalsin EnvironmentalSamples - SupplementI,"EPA-600/R-94-111, May 1994. Available 3 at NTIS, PB 94-184942. Method 100.1, "Analytical Method for Determination of Asbestos Fibers in Water," EPA-600/4-83-043, EPA, September 1983. 4 Available at NTIS, PB 83-260471. Method 100.2, "Determination of Asbestos Structure Over 10-:m In Length in Drinking Water," EPA-600/R-94-134, June 1994. 5 Available at NTIS, PB 94-201902. Methods for the Determination of Organic and Inorganic Compounds in Drinking Water - Volume 1,” document number EPA 6 815-R-00-014, August 2000. "Methods for the Determination of Inorganic Substances in Environmental Samples," EPA-600/R-93-100, August 1993. 7 Available at NTIS, PB94-121811. Available from Books and Open-File Reports Section, U.S. Geological Survey, Federal Center, Box 25425, Denver, CO 80225- 8 0425. Industrial Method No. 129-71W, "Fluoride in Water and Wastewater," December 1972, and Method No. 380-75WE, "Fluoride 9 in Water and Wastewater," February 1976, Technicon Industrial Systems, Tarrytown, NY 10591. Methods 150.1, 150.2 and 245.2 are available fromUSEPA, NERL, Cincinnati, OH45268. The identicalmethods were formerly 10 in "Methods for Chemical Analysis of Water and Wastes," EPA-600/4-79-020, March 1983. Method B-1011, "Waters Test Method for Determination ofNitrite/Nitrate in Water Using Single Column Ion Chromatography," 11 Millipore Corporation, Waters Chromatography Division, 34 Maple Street, Milford, MA 01757. Technical Bulletin 601 "Standard Method of Test for Nitrate in Drinking Water," July 1994, PN 221890-001, Thermo Orion, 12 500 Cummins Center, Beverly, MA 01915-9846. This method is identical to Orion WeWWG/5880, which is approved for nitrate analysis. ATI Orion republished the method in 1994, and renumbered it as 601, because the 1985 manual "Orion Guide to Water and Wastewater Analysis," which contained WeWWG/5880, is no longer available. GLI Method 2, "Turbidity," November 2, 1992, GLI International, 9020 W Dean Rd. Milwaukee, Wisconsin 53224. 13