上海交通大学:《材料热力学 Thermodynamics of materials》课程教学资源(课件讲稿)Chapter8 Phase rule
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Review Solutions Thermodynamic activity Partial molar quantities Relative partial molar quantities Entropy of mixing: ideal solution Enthalpy of mixing: ideal solution Graphical representation etc
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Review Solutions Thermodynamic activity Partial molar quantities Relative partial molar quantities Entropy of mixing: ideal solution Enthalpy of mixing: ideal solution Graphical representation etc
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1. Macrosates and Microstates宏观状态与微观状态 2. 微观状态数与最可几分布 3. Boltzmann假定与配置熵 4. 理想固溶体熵 5. 第三定律 6. Gibbs 公式 7. Boltzmann 分布* 8. 配分函数* 9. Fermi-Dirac 分布*
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Condition of equilibrium Phase equilibrium Clapeyron equation in vapor equilibria Variation of vapor pressure with particle size Second-order transition
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Property relation Functions F and G Partial molar quantities Property relation derived from U, H, F, and G etc
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Second law Functions F and G Property relation Property relation derived from U, H, F, and G etc
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Entropy 2nd law Heat engine etc
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Continue / Review previous 2nd law Entropy Reversible process Carnot cycle etc
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1th law continuous Adiabatic process: Joule-Thomson expansion 绝热过程 Equations of state 状态方程 Adiabatic compression or expansion 绝热压缩与膨胀 Enthalpies of formation 生成焓 Enthalpy changes in chemical reactions 焓变与化学反应 Adiabatic temperature change in chemical reactions 化学反 应的绝热温度 etc
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